ELECTRON ORBITS. These concepts are based upon Bohr’s supposition
that only a limited number of orbits are open to the electrons in
an atom, all others being prohibited for reasons which we still do
not fully understand, and that an electron is free to move from one
permitted orbit to another under the stimulus of radiation. Bohr
himself investigated the way in which the various permitted orbits
are arranged. Modern investigations indicate the need for a good deal
of revision of his simple concepts, but we shall discuss these in
some detail, partly because Bohr’s picture of the atom still provides
the best working mechanical model we have, and partly because an
understanding of his simple theory is absolutely essential to the
understanding of the far more intricate theories which are beginning to
replace it.
The hydrogen atom, as we have already seen, consists of a single
proton as central nucleus, with a single electron revolving around
it. The nucleus, with about 1840 times the weight of the electron,
stands practically at rest unagitated by the motion of the latter,
just as the sun remains practically undisturbed by the motion of the
earth round it. The nucleus and electron carry charges of positive and
negative electricity, and therefore attract one another; this is why
the electron describes an orbit instead of flying off in a straight
line, again like the earth and sun. Furthermore, the attraction between
electric charges of opposite sign, positive and negative, follows,
as it happens, precisely the same law as gravitation, the attraction
falling off as the inverse square of the distance between the two
charges. Thus the nucleus-electron system is similar in all respects
to a sun-planet system, and the orbits which an electron can describe
around a central nucleus are precisely identical with those which a
planet can describe about a central sun; they consist of a system of
ellipses each having the nucleus in one focus (p. 46).
Yet the general concepts of quantum-dynamics prohibit the electron from
moving in all these orbits indiscriminately. According to Bohr, the
electron of the hydrogen atom can move in a certain number of circular
orbits whose diameters are proportional to the squares of the natural
numbers 1, 4, 9, 16, 25, ...; it can also move in a series of elliptic
orbits whose greatest diameters are respectively equal to the diameters
of the possible circular orbits, although these elliptic orbits are
still further limited by the condition that their eccentricities
must have certain definite values. All other orbits are in some way
prohibited.
Public-domain text, read in full here on John Shaqi.
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