The unseen universe : $b or, physical speculations on a future stateStewart, Balfour
Religion
The unseen universe : $b or, physical speculations on a future state
Stewart, Balfour
Immortality; Religion and science
The term reversible is not here used in the popular sense in
which a mere reversal of the direction of motion of each part is
contemplated, _i.e._ what would be more properly termed ‘backing,’
it is used in the higher sense of taking an engine which converts a
certain quantity of the heat spent on it into work, while it lets the
rest down from the boiler to the condenser, and then spending upon
it the same amount of work with the result of taking back the heat
from the condenser, adding thereto the heat-equivalent of the work so
spent, and thus restoring the whole of its original loss in heat to
the boiler; simply in fact reversing all the results of the direct
action.[38]
* 107. Sir W. Thomson, in 1848, was the first to recall attention
to the work of Carnot, after Colding and Joule had published their
experimental discoveries; and he pointed out that the action of
the reversible engine gave what had been up to that time vainly
sought, an absolute definition of temperature—a definition, that is,
altogether independent of the properties of any particular species of
matter. In fact it is obvious that as reversibility in the sense we
have just explained is the stamp of perfection in a heat-engine, all
reversible engines, whatever be the working substance, will, under
the same circumstances, that is to say, _with the same temperatures
of boiler and condenser_, convert the same fraction of the heat spent
on them into work. This, of course, still leaves wide scope for
choice of a definition of temperature: but that finally determined
on by Thomson was chosen (in consequence of a hint from some
experimental results of Joule) so as to make the absolute measurement
agree nearly with that of the long-familiar air-thermometer. It
therefore stands as follows:—
_The heat taken in by a perfect engine is to the heat given out by it
in the same proportion as the absolute temperature of the boiler to
that of the condenser._
Of course it is hardly necessary to state that it is only the excess
of the heat taken in over that given out by any engine that can have
been converted into available work. This follows at once from the
conservation of energy.
Experiments carried on by Joule and Thomson[39] together have shown
that the absolute zero of temperature is nearly 274° below zero of
the centigrade scale; so that on the absolute scale the temperature
of melting ice is 274°, while that of water boiling under the
standard pressure is 374°.
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