The Wonder Book of Volcanoes and EarthquakesHouston, Edwin J. (Edwin James)
Science
The Wonder Book of Volcanoes and Earthquakes
Houston, Edwin J. (Edwin James)
Earthquakes; Volcanoes
Moissan, however, was not the first to produce diamonds artificially.
As soon as Lavoisier had experimentally shown that the chemical
composition of the diamond and carbon are the same, efforts were made
to convert charcoal into diamonds, and Despretz, as early as 1849,
by means of the combined influence of a powerful burning glass, the
oxyhydrogen blowpipe, and the carbon voltaic arc obtained a very high
temperature. He claims by this temperature to have been able to change
carbon into a few microscopic diamonds. It is quite possible, in the
light of later investigations, that Despretz may have been mistaken
in his belief that he had actually produced diamonds; but whether
this be so or not, he was certainly one of the pioneers in this early
transformation of charcoal.
Theoretically, all that would be required in order to change the
non-crystalline form of carbon into the diamond, would be to
subject the carbon to a temperature sufficiently high to fuse it
and then permit it slowly to crystallize. Could this be done, there
should be no trouble in transforming any amount of coal into any
equal amount of diamonds. But the transformation is by no means as
simple as might be supposed. It is not that the temperature of the
carbon cannot be raised to its point of fusion, but that as soon
as a certain temperature has been reached, the carbon, instead of
fusing or melting, is suddenly volatilized or turned into vapor.
There is no doubt that this is done. Thousands of feet of carbon
rods are volatilized every night in the arc lamps of our cities,
but the trouble is that this carbon vapor so formed, when cooled,
or condensed, is not converted into the exceedingly hard, clear,
crystalline diamond, but into the soft, dull black graphite or
plumbago.
Now the process adopted by Moissan in order to cause volatilized
carbon, or carbon vapor, to condense in the form of crystalline
diamonds was practically as follows: he placed pieces of pure carbon
inside a very strong steel tube, such, for example, as would be formed
by boring a short cylindrical hole in a piece of strong thick steel,
and placing a small quantity of carbon inside the tube so formed.
Closing the open end of the tube by means of a tightly fitting screw
plug, he volatilized the carbon inside the tube. The steel, tube, and
plug formed an electric furnace, for, as soon as he passed an electric
current through it, the temperature at once became high enough to
volatilize the carbon.
Under these circumstances the carbon vapor was subjected to great
pressure owing to the limited space in which it was liberated. As soon
as this mass of dense vapor had been formed, he seized the steel tube
with a pair of furnace tongs, and plunged it below the surface of cold
water in a bucket.
Public-domain text, read in full here on John Shaqi.
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