The delicacy of spectrum analysis may be imagined from the fact that a
quantity of sodium amounting to less than the _two-millionth_ of a grain
can be detected by its means. Indeed, it has taught us that sodium in
one form or other exists almost everywhere. This mode of analysis is
only serviceable to indicate the composition of any salt or other
substance, the quantities of the different elements found by its use
having no influence on the appearances brought out by the prism. Thus, a
substance which has only been contaminated with sodium from being
handled by warm fingers, will show the yellow bands as strongly as if it
contained a large proportion of that metal.
For ordinary experiments in spectrum analysis the apparatus used is very
simple. It consists of a tube with a fine slit at one end, and a convex
lens at the other, for concentrating the light from the coloured flame
upon the centre of the prism. After the light passes through the prism,
it is examined by a small telescope of low magnifying power. The lamp
used may be either a spirit-lamp or a colourless gas flame into which
the substance to be examined is introduced upon a platinum wire.
We now come to another very important discovery, made by means of our
prism and narrow slit—the determination of the composition of the
photosphere or mass of luminous vapour surrounding the body of the sun.
A simple experiment will show how this brilliant discovery was arrived
at. The light of a candle or other flame containing incandescent _solid_
matter is passed through the spectroscope, and is found to decompose
into a continuous spectrum, uninterrupted by dark lines. Between the
light and the slit a spirit-lamp is placed, but no difference in the
appearance of the spectrum is perceived. Introduce, however, the
smallest portion of a soda salt into the non-luminous flame of the
second-lamp, and a broad black line is immediately seen, crossing the
middle of the yellow portion of the band of colour. Remove the sodium
flame and the band disappears; but do the same with the lamp producing
the spectrum, and the spectrum of course disappears, and the dark band
caused by the sodium flame is changed to the yellow line produced by
that metal. The same experiments may be tried with potassium, strontium,
and other metals; and we shall always find that when a coloured flame is
introduced between an incandescent solid and its continuous spectrum, it
produces a series of black lines corresponding to the substances by
which it is coloured. Thallium, in like manner, would give a black band
in the middle of the green, and indium a similar one in the indigo.
(Fig. 6, Frontispiece).
Public-domain text, read in full here on John Shaqi.
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