Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
Sulphuric acid is extensively employed in very many trades, is used even
for some domestic purposes, and is consequently familiar to every one.
Hence it is the mineral acid which has been most commonly used as a
poison, especially for committing suicide. Of 35 cases of poisoning with
the mineral acids which occurred in England in the years 1837 and 1838,
32 were caused by this acid (p. 90).
SECTION I.—_Of the Tests for Sulphuric Acid._
Sulphuric acid is known as a poison chiefly in the form of the
concentrated commercial acid. But a few cases of poisoning have also
been produced by blue-liquor or the solution of indigo in strong
sulphuric acid; and one instance[233] has been recorded of poisoning
with the aromatic sulphuric acid of the Pharmacopœias, which is an
infusion of aromatics in a mixture of sulphuric acid, ether and alcohol.
In the following remarks on its tests, it will be sufficient to consider
it _first_ in the concentrated form,—_secondly_, in a state of simple
dilution,—and _thirdly_, when mixed with various impurities, more
especially with vegetable and animal matter. The acid solution of indigo
may be known by the tests for the concentrated acid, and its blue
colour, removable by a solution of chlorine; and the aromatic sulphuric
acid may be distinguished by its odour and the tests for the diluted
acid.
1. _When concentrated_ it is oily-looking, colourless, or brownish from
having acted on organic particles, without odour, much heavier than
water, and capable of quickly corroding animal substances. If from these
properties, and its effect in reddening litmus, its exact nature be not
considered obvious, it may be heated with a few chips of copper; when
sulphurous acid is disengaged and may be readily recognised by its
odour.
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