Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
In all medico-legal analyses for nitric acid, care must be taken that
the different reagents used are free of this acid, and also of nitrates.
Sulphuric acid often contains a little nitric, or rather nitrous acid;
which may be discovered by the sulphuric acid becoming brown or dark-red
when a solution of proto-sulphate of iron is gently poured over it in a
test-tube; and which may be removed either by boiling the acid with a
few grains of sugar, according to the formula of the Edinburgh
Pharmacopœia, or, as Orfila directs, by boiling it with sulphate of
ammonia.
SECTIONS II. III. IV.—_Of the Action, Symptoms, Morbid Appearances, and
Treatment of Poisoning with Nitric Acid._
All the observations made on these topics under the head of sulphuric
acid apply, with few exceptions, to the nitric acid also. A few
statements therefore on the peculiarities ascertained to exist in the
latter case are all that will be required in the present sections.
Nitric acid is not less powerful as a corrosive and irritant than
sulphuric acid. It will act with energy as an irritant even when
considerably diluted, for example with six or eight parts of water or
even more.—The lips which are rendered at first whitish by all the
acids, and eventually brownish by sulphuric acid, becomes soon yellow
with nitric acid. The tongue too sometimes acquires a yellow colour
instead of a white glazed appearance; but this character is not
invariable.—All spots caused by it on the skin become speedily yellow,
and long retain this hue; or if the tint become dull, which generally
happens in a few days, it is enlivened and the yellow colour restored
for a time, by ammonia, potash, soda, or soap.—An important fact, for
which toxicology is indebted to Professor Orfila, is that the acid may
be often found in the urine, both when it had been swallowed, and when
it had been introduced through the medium of the cellular tissue.[311]
It is to be discovered by the process for compound mixtures. Orfila adds
that he has hitherto been unable to find it in the liver or spleen.
A difference of tint in the lining membrane of the mouth and gullet is
the only difference observed in the morbid appearances caused by nitric
and sulphuric acid. The former sometimes renders these parts yellow; but
this appearance is far from being invariable.
The treatment in both instances is the same in every respect.
III.—OF POISONING WITH HYDROCHLORIC ACID.
This acid occurs more rarely than any of the other mineral acids in
medico-legal cases; a fact which appears singular enough on considering,
that it is a powerful corrosive, and more perhaps in the hands of the
working-classes than any other.
SECTION I.—_Of the Tests for Hydrochloric Acid._
Like the other acids, hydrochloric acid occurs in the concentrated
shape, in a state of simple dilution, and mixed with various matters,
especially from organic kingdoms.
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