Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
I have found that when this process was applied to a decoction of an
ounce of beef in six ounces of water, with which one grain of anhydrous
oxalic acid had been mixed, all the tests acted characteristically on
the solution ultimately procured. I have farther found, that when two
grains of oxalate of lime, which correspond with one grain of oxalic
acid, were mixed with a similar decoction in which some fragments of
beef were purposely left to complicate the process, a solution was
eventually obtained, which gave with muriate of lime a white precipitate
insoluble in a little muriatic acid, with sulphate of copper a
greenish-white precipitate also insoluble in a little muriatic acid, and
with nitrate of silver a white precipitate which fulminated and was
almost all dispersed, but left a little charcoal, owing to its
containing a small proportion of animal matter. In a case which lately
happened in London, every test acted as here described, except that the
oxalate of lime did not fulminate, owing to the presence of organic
impurities.[396] In order to try the test of fulmination in such
circumstances, it is essential to dry the precipitated oxalate of silver
thoroughly before raising the temperature to the point at which
fulmination usually occurs.
The process now recommended is both delicate and accurate. An objection
has been advanced against it,—that acetate of lead will throw down
chloride of lead as well as the oxalate of lead; that both will
subsequently be decomposed by the sulphuretted-hydrogen? and that the
hydrochloric acid thus brought into the solution with the oxalic acid
will be precipitated by the nitrate of silver, and form a mixture of
salts which will not fulminate characteristically.[397] This objection
is not well founded. Chloride of lead being soluble in thirty parts of
temperate water, it will seldom be thrown down from such fluids as occur
in medico-legal inquiries; and besides it is easily removed, as I have
ascertained, by washing the precipitate with moderate care on the
filter.
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