Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
_Potass_ in its caustic state, as usually met with in the shops, forms
little gray-coloured cylinders or cakes which have a radiated,
crystalline fracture, and an excessively acrid caustic taste, and feel
soapy if touched with the wet finger. It deliquesces rapidly in moist
air, and then attracts carbonic acid from the atmosphere. It is easily
fused by heat, and is exceedingly soluble in water. The solution has a
strong alkaline reaction on vegetable colours, restoring reddened litmus
to blue, turning syrup of violets or infusion or red cabbage to green,
and rendering infusion of turmeric brown. It is distinguished from the
alkaline earths when in solution, by not precipitating with carbonic or
sulphuric acid, and from soda by the tests to be presently mentioned for
its carbonate.
_Carbonate of potash_ [subcarbonate, salt of tartar], is usually sold,
when pure, in small white grains, formed by melting the salt and
stirring it rapidly as it cools. In its impure state it is called in
this country potashes, and when somewhat purified, pearl ash. It has
then a mixed grayish, yellowish, or bluish colour, and is sold in
crumbly lumps of various sizes. In every state it is deliquescent and
very caustic. It cannot be crystallized. It gives out carbonic acid gas
with the addition of any stronger acid, such as sulphuric, muriatic, or
acetic acid. Its solution precipitates yellow with the chloride of
platinum, gives a crystalline precipitate with perchloric acid, when the
salt forms not less than a fortieth or fiftieth part,—is similarly acted
on by a considerable excess of tartaric acid, if the salt constitute
about a thirtieth of the fluid,—and yields with the soluble salts of
baryta a white precipitate soluble in nitric acid.
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