Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
The conclusiveness of this process depends upon the fact, that absolute
alcohol cannot dissolve from solid organic substances such a proportion
of lactate, tartrate, acetate, sulphate, or phosphate of potash, or
chloride of potassium, as to be acted on by chloride of platinum or
perchloric acid.[430]—It is to be observed that carbonate of potash
singly is insoluble in absolute alcohol; but it becomes soluble in that
fluid, when it is conjoined with various organic matters. Hence it is
that this process, intended fundamentally for caustic potash alone, is
applicable to carbonate of potash also.
_Process for Soda and its Carbonate in Organic Mixtures._—These
substances may be separated by the method just described for potash. If
the alcoholic solution of the extract of the suspected matter be
alkaline in its action on litmus, and be afterwards found to contain
soda or its carbonate, the evidence of these substances having been
derived from without is satisfactory, because the carbonate of soda
contained in many animal matters cannot be so detached. But if no
indications of the presence of soda be thus obtained, it is not enough
that soda be found in the alcoholic solution of the incinerated
alcoholic extract, because the natural carbonate of soda of animal
matter may be separated in that manner.[431]
SECTION II.—_Of the Action of the fixed Alkalis, and the Symptoms they
cause in Man._
The action of the two fixed alkalis and their carbonates on the animal
system is so nearly the same, that the facts which have been ascertained
in respect to one of them will apply to all the rest. The operation of
potass and its carbonate has been carefully investigated by Professor
Orfila,[432] and by M. Bretonneau of Tours.[433]
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