Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
A very simple and decisive test for fly-powder is derived from the
effect of heat. If it is heated in a tube two substances are sublimed,
first a white crystalline powder, and then a bright metallic crust, the
former being the white oxide, the latter the metal. The metallic crust
thus formed possesses physical properties, which distinguish arsenic
from all other substances, capable of being sublimed by a low heat: The
surface next the tube is very like polished steel, being a little darker
in colour, but equal in brilliancy and polish; and the inner surface is
either brilliantly crystalline to the naked eye, like the fracture of
cast-iron, or has a dull grayish-white colour, but appears crystalline
before a common magnifying lens of four or five powers. If these
characters be attended to, particularly the appearance of the inner
surface, it appears to me scarcely possible to mistake for an arsenical
crust any other substance which can be sublimed by any of the methods
for subliming arsenic.
If a farther test should be desired, it is only necessary, as was first
proposed by Dr. Turner of London,[491] to chase the crust up and down
the tube with the spirit-lamp flame till it is all oxidated, when little
octaedral crystals of adamantine lustre are formed, on which, either
with the naked eye or with the aid of a common lens, triangular facettes
may be distinguished.
The niceties to be attended to in applying the preceding tests will be
considered presently under the head of the next compound, the
sesquioxide.
2. _Of the Tests for Arsenious Acid._
Arsenious acid, the sesquioxide, or white oxide of arsenic, usually
called white arsenic, or simply arsenic, is the most common and
important of all the arsenical preparations.
It is met with in the shops in two forms,—as a snow-white gritty powder,
and in solid masses generally opaque, but sometimes translucent. When
newly sublimed it is in translucent or even almost transparent masses of
a vitreous lustre, conchoidal fracture and sharp-edged. By keeping it
becomes opaque and white. The nature of the change has not been
determined; but some alteration is certainly effected, for Guibourt, who
has examined both varieties with care, found that the opaque variety is
more soluble in water than the other. He adds that the former is
alkaline, the latter acid, in its action on litmus paper; but I have
always found the opaque variety acid.[492] The powder soon becomes
analogous to the opaque variety of the oxide in mass.
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