Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
His discovery consists in the observation, that, if hydrogen gas be
disengaged by the action of sulphuric acid or zinc in a fluid containing
arsenic dissolved in any form, arseniuretted-hydrogen gas is disengaged
along with the hydrogen; and that if the two gases be burnt together in
a fine flame, metallic arsenic is deposited on a white porcelain surface
held in the flame, and oxide of arsenic if the porcelain be held
immediately above it.[524] The production of a brilliant mirror-like
crust in the former case, and of a white powdery one in the other,
constituted Marsh’s test as originally proposed; and it was at first
conceived to furnish unimpeachable evidence of the detection of arsenic.
Afterwards many inquirers, and among them the discoverer himself, became
satisfied that certain fallacies stand in the way of a conclusion based
on such simple premises. Various supplementary tests were in consequence
proposed. And at length it seems to be agreed, that the proper mode of
applying Marsh’s discovery is to employ a succession of tests, of which
that originally pointed out by him is the first. A vast variety of
methods of analysis founded on this principle have been proposed by
British and continental chemists. It would be tedious and unprofitable
to discuss or even to state them here. The reader will probably be
satisfied with a reference to the most important of them[525] and with a
description of that process, which appears to me, from repeated trials
in medico-legal practice, to be at once most convenient, delicate, and
conclusive.
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