Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
The primary fact, and the qualification of it, are in my opinion of
equally little medico-legal importance. It is not likely that such
enormous masses of material will ever be operated on again, as those
which were made use of in some late, French trials, and for which great
iron pots were found indispensable;—because it has been proved that
absorbed arsenic is chiefly to be met with in particular organs or
secretions, such as the liver and urine. Besides, a false importance has
been attached to the enthusiastic analyses of the whole human carcase,
with which some French chemists have been astounding the minds of the
scientific world, as well as the vulgar, on the occasion of certain late
trials for poisoning. I confess I could not find fault with a jury, who
might decline to put faith in the evidence of poisoning with arsenic,
when the analyst, after boiling an entire body, with many gallons of
water, in a huge iron cauldron, making use of whole pounds of sulphuric
acid, nitric acid, and nitre, and toiling for days and weeks at the
process, could do no more than produce minute traces of the poison. What
man of common sense will believe, that, with such bulky materials and
crude apparatus, it is possible to guard to a certainty against the
accidental admission of a little arsenic? At all events I am much
mistaken if any British jury would condemn a prisoner on such
evidence,—or any British chemist find fault with them for declining to
do so.
3. _Arsenic may have existed in antidotes administered during life._—It
is now generally known, that the only chemical antidote for arsenic is
the hydrated sesquioxide of iron. But this substance appears
occasionally to contain a little arsenic, obviously derived from the
compound of iron whence the oxide is prepared.[544] Such an adulteration
must be rare in what is prepared by the ordinary processes, according to
which the oxide of arsenic ought to remain in solution. The only
effectual mode, however, of guarding against this source of error, when
the antidote has been administered, is to examine a portion of the stock
whence the patient was supplied, by dissolving it in an excess of
sulphuric acid, and subjecting it to Marsh’s test.
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