The degree of rapidity with which an explosive substance undergoes
metamorphosis, as also the nature and results of such change, are in
the greater number of instances susceptible of several modifications,
by variation of the circumstances under which the conditions essential
to chemical change are fulfilled. Excellent illustrations of the modes
by which such modifications may be brought about are furnished by
gun-cotton, which may be made to burn very slowly and almost without
flame, to inflame with great rapidity, but without development of
great explosive force, or to exercise a violent destructive action;
according as the mode of applying heat, the circumstances attending
its application, and the mechanical conditions of the explosive agent
are modified. Nitro-Glycerin or Glonoin, which bears some resemblance
to chloride of nitrogen in the suddenness of its explosion, requires
the fulfillment of special conditions for the full development of its
explosive force. Its explosion by the simple action of heat can be
accomplished only when the source of heat is applied for a considerable
time in such a way that chemical decomposition is established in some
portion of the mass, and is favored by the continued application of
heat to that part; under these circumstances the chemical change
proceeds with very rapidly accelerating violence, and eventually brings
about a sudden transformation of the heated portion into gaseous
products, which transformation is instantly communicated throughout
the mass of Nitro-Glycerin, so that confinement of the substance is
not necessary to develop its full explosive force. This result can be
obtained more expeditiously, and with greater certainty, by exposing
the substance to the concussive action of a detonation produced by the
ignition of a small quantity of fulminating powder placed in contact
with or near to the Nitro-Glycerin.
The development of the violent explosive action of Nitro-Glycerin,
freely exposed to air, through the agency of a detonation, was
regarded until recently as a peculiarity of that substance; but Abel’s
experiments have shown that gun-cotton and other explosive compounds
and mixtures do not necessarily require confinement for the full
development of their explosive force; this result being obtained (and
very readily in some instances, especially in that of gun-cotton) by
means similar to those applied in the case of Nitro-Glycerin, viz.: by
the percussive action of a detonation.
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