Useful Knowledge: Volume 1. Minerals: Or, a familiar account of the various productions of natureBingley, William
History
Useful Knowledge: Volume 1. Minerals: Or, a familiar account of the various productions of nature
Bingley, William
Commercial products; Geology, Economic; Natural history
203. _GLAUBER SALT, or SULPHAT of SODA, is a salt which consists of soda
(200) in combination with sulphuric acid (24). It occurs in an
efflorescent or powdery state, on the borders of salt lakes; or, more
commonly, in a state of solution, in certain mineral waters._
This salt, which was originally discovered by a German chemist whose
name was Glauber, has a nauseously bitter and saline taste. It is found,
in an efflorescent state, on meadow ground at Eger, in Bohemia; and on
the walls of old galleries in mines, at Grenoble, in France. It is also
abundant in the ashes of some kinds of vegetables, especially of sea
weeds. The waters of the Mediterranean yield a great proportion of it;
and the Glauber salt used for commercial purposes is chiefly prepared
from sea─water, or by decomposing common salt, in order to procure
muriatic acid (29). It may also be obtained by saturating soda with
sulphuric acid (24).
The use of this salt in medicine is well known; and, in some countries,
it is employed as a substitute for soda (200), in the manufacture of
white glass. It ought to be kept in well─corked bottles, as otherwise
the crystals soon fall into powder.
The following is a pleasing experiment, which shows a singular and
almost instantaneous crystallization of Glauber’s salt. Dissolve this
salt by adding portions of it gradually to water kept boiling until the
water will dissolve no more. Pour the solution, whilst boiling, into
common medicine phials previously warmed, and immediately cork them. Set
the phials in a quiet place without shaking them. The solution, when
cool, will remain perfectly fluid till the cork is taken out; but the
moment this is done, and the air is admitted, it will begin to
crystallize on its upper surface, in fine satin─like crystals, which
will shoot downward, like a dense white cloud. In this act so much heat
becomes evolved as to make the phial feel sensibly warm to the hand.
When the crystallization is complete, the whole mass generally becomes
so solid, that, on inverting the bottle, not a drop of it will fall out.
If the crystallization should not immediately ensue on opening the
phial, this may instantly be effected by dropping into it a minute
crystal of the same salt. The experiment may be exhibited any number of
times afterwards, by merely placing the phial in boiling water, till the
salt it contains be again completely liquefied; and letting it stand, as
before, to cool.
204. _BORAX is a salt composed of boracic acid (28) and soda (200), and
is imported chiefly from the East Indies, in the form of a brownish
grey, impure, shapeless salt, of sweetish taste; or in detached
prismatic crystals, each about an inch in length._
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