The sandstone of the Blue Mountains is at least 1,200 feet thick, and in some parts is apparently of greater thickness; it consists of small grains of quartz, cemented by white earthy matter, and it abounds with ferruginous veins. The lower beds sometimes alternate with shales and coal: at Wolgan I found in carbonaceous shale leaves of the Glossopteris Brownii, a fern which so frequently accompanies the coal of Australia. The sandstone contains pebbles of quartz; and these generally increase in number and size (seldom, however, exceeding an inch or two in diameter) in the upper beds: I observed a similar circumstance in the grand sandstone formation at the Cape of Good Hope. On the South American coast, where tertiary and supra- tertiary beds have been extensively elevated, I repeatedly noticed that the uppermost beds were formed of coarser materials than the lower: this appears to indicate that, as the sea became shallower, the force of the waves or currents increased. On the lower platform, however, between the Blue Mountains and the coast, I observed that the upper beds of the sandstone frequently passed into argillaceous shale,—the effect, probably, of this lower space having been protected from strong currents during its elevation. The sandstone of the Blue Mountains evidently having been of mechanical origin, and not having suffered any metamorphic action, I was surprised at observing that, in some specimens, nearly all the grains of quartz were so perfectly crystallised with brilliant facets that they evidently had not in their PRESENT form been aggregated in any previously existing rock. (I have lately seen, in a paper by Smith (the father of English geologists), in the “Magazine of Natural History,” that the grains of quartz in the millstone grit of England are often crystallised. Sir David Brewster, in a paper read before the British Association, 1840, states, that in old decomposed glass, the silex and metals separate into concentric rings, and that the silex regains its crystalline structure, as is shown by its action on light.) It is difficult to imagine how these crystals could have been formed; one can hardly believe that they were separately precipitated in their present crystallised state. Is it possible that rounded grains of quartz may have been acted on by a fluid corroding their surfaces, and depositing on them fresh silica? I may remark that, in the sandstone formation of the Cape of Good Hope, it is evident that silica has been profusely deposited from aqueous solution.