Worlds in the making: The evolution of the universeArrhenius, Svante
Science
Worlds in the making: The evolution of the universe
Arrhenius, Svante
Cosmogony
We have, moreover, seen that the highest strata of the sun are
distinguished by line spectra, suggestive of simple chemical compounds,
while at greater depth in the sun-spots chemical combinations occur
which are characterized by band spectra. It is quite incorrect to
assert that high temperatures must necessarily decompose all chemical
compounds into their elements. The mechanical theory of heat teaches
us only that at rising temperatures products are formed whose
formation goes hand in hand with an absorption of heat. Thus, at a
high temperature, ozone is formed from oxygen, although ozone is more
complex in composition than oxygen, and by this reaction 750 calories
are consumed when one gramme of oxygen is transformed into one gramme
of ozone. We likewise know that in the electric arc, at a temperature
of about 3000°, a compound is formed under consumption of heat by the
oxygen and nitrogen of the atmosphere. A new method for the technical
preparation of nitric acid from the nitrogen of the air is based upon
this reaction. Again, the well-known compounds benzene and acetylene
are formed from their elements, carbon and hydrogen, under absorption
of heat. All these bodies can only be synthesized from their elementary
constituents at high temperatures. We further know from experience
that the higher the temperature at which a reaction takes place, the
greater, in general, the amount of heat which it absorbs.
A similar law applies to the influence of pressure. When the pressure
is increased, such processes will be favored as will yield products of
a smaller volume. If we imagine that a mass of gas rushes down from a
higher stratum of the sun into the depths of the sun’s interior, as
gases do in sun-spots, complex compounds will be produced by virtue
of the increased pressure. This pressure must increase at an immense
rate towards the interior of the sun, by about 3500 atmospheres
per kilometre. The gases which dissociate into atoms at the lower
pressures and the higher temperatures of the extreme solar strata above
the photosphere clouds enter into chemical combination in the depths
of the spots, as we learn from spectroscopic examination. Owing to
their high temperatures, these compounds absorb enormous quantities of
heat in their building up, and these quantities of heat are to those
which are concerned in the chemical processes of the earth in the same
ratio as the temperature of the sun is to that at which the chemical
reactions are proceeding on the earth. As these gases penetrate
farther into the sun, temperature and pressure are still more and more
increased, and there will result products more and more abounding in
energy and concentration. We may, therefore, imagine the interior
of the sun charged with compounds which, brought to the surface of
the sun, would dissociate under an enormous evolution of heat and an
enormous increase of volume. These compounds have to be regarded as
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