The electron, its isolation and measurement and the determination of some of its properties — John Stuart Mill — John Shaqi
The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
All of the changes of charge shown in Table IV were spontaneous
changes, and it has been assumed that all of these changes were
produced by the capture of ions from the air. When a negative drop
suddenly increases its speed in the field, that is, takes on a larger
charge of its own kind than it has been carrying, there seems to be no
other conceivable way in which the change can be produced. But when
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the charge suddenly decreases there is no a priori reason for
thinking that the change may not be due as well to the direct loss of a
portion of the charge as to the neutralization of this same amount of
electricity by the capture of a charge of opposite sign. That, however,
the changes do actually occur, when no X-rays or radioactive rays are
passing between the plates, only by the capture of ions from the air,
was rendered probable by the fact that drops not too heavily charged
showed the same tendency on the whole to increase as to decrease in
charge. This should not have been the case if there were two causes
tending to decrease the charge, namely, direct loss and the capture of
opposite ions, as against one tending to increase it, namely, capture
of like ions. The matter was very convincingly settled, however, by
making observations when the gas pressures were as low as 2 or 3 mm.
of mercury. Since the number of ions present in a gas is in general
directly proportional to the pressure, spontaneous changes in charge
should almost never occur at these low pressures; in fact, it was
found that drops could be held for hours at a time without changing.
The frequency with which the changes occur decreases regularly with
the pressure, as it should if the changes are due to the capture of
ions. For the number of ions formed by a given ionizing agent must vary
directly as the pressure.
Again, the changes do not, in general, occur when the electrical field
is on, for then the ions are driven instantly to the plates as soon
as formed, at a speed of, say, 10,000 cm. per second, and so do not
have any opportunity to accumulate in the space between them. When
the field is off, however, they do so accumulate, until, in ordinary
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air, they reach the number of, say, 20,000 per cubic centimeter. These
ions, being endowed with the kinetic energy of agitation characteristic
of the temperature, wander rapidly through the gas and become a part
of the drop as soon as they impinge upon it. It was thus that all the
changes recorded in Table IV took place.