A-B-C of ElectricityMeadowcroft, Wm. H. (William Henry)
Science
A-B-C of Electricity
Meadowcroft, Wm. H. (William Henry)
Electricity
Here, you will see, the carbon is placed in the porous cup, while the
zinc is outside in the glass jar. In the glass cell with the zinc
is usually used water made slightly acid, and the strong solution of
sulphuric acid and bichromate of potash (or chromic acid) is poured in
the porous cup, where the carbon is placed.
The strong solution penetrates the porous cup very slowly and gets to
the zinc, when it immediately produces a current of electricity. But
the acid does not get at the zinc so freely as it does in the battery
without a porous cup, and, consequently, neither the acid nor the zinc
is so rapidly used up.
Where porous cups are used, the batteries will give a continuous
current for a very much longer time than without them, and will,
sometimes, give many hours' work every day for several months without
requiring any change of solution.
_Polarization._--There is one other reason why a longer working time
can be had from a battery with a porous cup, and that is, in a battery
without a porous cup the action of the acid upon the zinc is so rapid
that the carbon plates become covered with gas, and, therefore, the
proper action by the acid cannot take place upon them. Thus, the
battery ceases to work, and is said to be "polarized." When a porous
cup is used, the action of the acid upon the zinc is slow enough to
give off only a small amount of gas, and thus the acid has a chance to
act upon the carbon plates and develop a steady current of electricity.
THE WORK DONE BY BATTERIES
The pressure and quantity of electricity given off continuously by open
and closed circuit batteries is very different.
The pressure (or "electromotive force") of one cell of an ordinary
open-circuit battery is only about one volt, and the current is usually
very much less than one ampère, except in a dry cell, which may give
more.
In the closed-circuit batteries described, the electromotive force
of each cell is about two volts, while the current varies from 1 to
perhaps 50 ampères, according to the size of the zinc and carbon plates.
It would not matter if you made one cell as big as a barrel, nor if you
put in a _dozen carbons and zincs_, the _electromotive force would not
exceed the volts mentioned for each type of battery_, but the _ampère
capacity would be greater_ than in a smaller cell on account of the
larger size of the carbon and zinc plates.
_Internal Resistance._--There is one other point which affects the
number of ampères which can be obtained from a closed-circuit battery,
and that is whether there is a large or small internal resistance in
the battery itself.
This depends upon the solution which is used and the arrangement of the
plates.
If there is a high resistance in the battery itself (called "internal
resistance"), the electricity must do work to overcome this resistance
before it can get out of the battery to do useful work through the
wires, and, consequently, the capacity in ampères is limited.
Public-domain text, read in full here on John Shaqi.
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