A Brief Account of Radio-activityVenable, F. P. (Francis Preston)
Science
A Brief Account of Radio-activity
Venable, F. P. (Francis Preston)
Radioactivity
Another method of obtaining the same result is to dissolve
crystallized uranium nitrate in ether. Two layers of solution are
formed, one ether and the other water coming from the water of
crystallization. The aqueous layer is active, while the water layer is
inactive. Similarly, by adding barium chloride solution to a solution
of a salt of uranium and then precipitating the barium as sulphate,
the activity is transferred to this precipitate. These experiments
give proof of the formation and separation of a radio-active body by
ordinary chemical operations.
So, too, in the case of thorium salts a substance can be obtained by
means of ammonium hydroxide which is several thousand times more
active than an equal weight of the original salt. After standing a
month, the separated material has lost its activity and the thorium
salt has regained it. Here, again, there is the formation, separation,
and loss of a radio-active body.
Conclusions Drawn
Now, these are ordinary chemical processes for the separation of
distinct chemical individuals. The results, therefore, lead naturally
to the conclusions: (1) it would seem that uranium and thorium are
themselves inactive and the activity is due to some other substance
formed by these elements; (2) this active substance is produced by
some transformation in those elements, for on standing the activity
is regained. This latter conclusion is startling, for it indicates a
change in the atom which, up to the time of this discovery, was deemed
unchangeable under the influence of such physical and chemical changes
as were known to us.
Search for New Radio-active Bodies
The search for new radio-active bodies and the study of their
characteristics has been systematically and successfully carried on.
The bodies obtained in the above experiments were named uranium _X_
and thorium _X_, respectively. Further, it became clear from the
investigation of uranium minerals that radium, polonium, actinium, and
ionium originated from uranium. From thorium minerals a body was
separated called mesothorium, which was analogous to radium. Both
thorium and radium were found to give off a radio-active gas. The
first lost half of its activity in less than one minute. The second
was more stable and lost half of its activity in about four days. The
name radium emanation was given to the latter and it was found
chemically and physically to belong to the class of monatomic or noble
gases, such as helium, argon, neon, etc., which had been discovered by
Ramsay. In some cases the chemical action was determined and these new
bodies were found analogous to well-known elements, as radium to
barium, polonium to bismuth. The physical properties were investigated
and, where possible, spectra were mapped and atomic weights
determined.
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