A Brief Account of Radio-activityVenable, F. P. (Francis Preston)
Science
A Brief Account of Radio-activity
Venable, F. P. (Francis Preston)
Radioactivity
Manifestly, a state of equilibrium will be reached when the rate of
loss of activity of the matter already produced is balanced by the
activity of the new matter produced. This equilibrium and the
knowledge of the rate of decrease in general will have little value if
this rate, like chemical changes, is subject to the influence of
chemical and physical conditions. The rate of decrease has been found
to be unaltered by any known chemical or physical agency. For
instance, neither the highest temperatures applicable nor the cold of
liquid air have any appreciable effect.
Equilibrium Series
In order to measure the disintegration of a radio-active body in units
of time so that the rate may be comparable with that of other
radio-active bodies, the relation between the amounts under
consideration must be a definite one. For this purpose equal weights
of the bodies are not taken, but use is made of the amounts which are
in equilibrium with a fixed amount of the parent substance.
One gram of radium has been settled upon as the standard for that
series and a unit known as the "curie" has been adopted to express the
equilibrium quantity of radium emanation. Thus, a curie of radium
emanation (or niton) is the weight (or, as this is a gas, the volume
at standard pressure and temperature) of the emanation in equilibrium
with one gram of radium. This, by calculation and experiment, is found
to be 0.63 cubic millimeter. When this amount has been produced by one
gram of radium, the formation and decay will exactly balance one
another. This is, therefore, one curie of emanation.
The measurement of the rate of decay is difficult but can be carried
out with great accuracy, even down to seconds, in the case of certain
short-lived bodies. Errors crept in at first from the failure to
completely separate the substances produced in the series, and
sometimes because of the simultaneous production of two substances.
As stated, the decay follows an exponential law. The time required for
the decay of activity to half-value does not mean, therefore, that
there will be total decay in twice that time. Thus the half-value
period for uranium _X_ is about 22 days. The period for complete decay
is about 160 days. This half-value period corresponds to the
half-value recovery period of uranium, which is also 22 days.
These were the earlier figures obtained for uranium _X_ and they
illustrate some of the difficulties surrounding such determinations.
It was found later that the body examined as uranium _X_ was really a
constant mixture and of course the decay and recovery periods were
also composite. It required later and very skilful work to separate
them into the bodies indicated in the disintegration series.
The half-value period for thorium _X_ is much shorter, namely, a
little over four days, and this is also the recovery period for
thorium _X_. The plotted decay and recovery curves will intersect at
this point.
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