A Brief Account of Radio-activityVenable, F. P. (Francis Preston)
Science
A Brief Account of Radio-activity
Venable, F. P. (Francis Preston)
Radioactivity
The greater part of the tremendous energy evolved by radium is due to
the emission of the alpha particles, and in comparison the beta and
gamma rays together supply only a small fraction. This energy may be
measured as heat. It was first observed that a radium compound
maintained a temperature several degrees higher than that of the air
around it. The rate of heat production was later measured by means of
an ice calorimeter and also by noting the strength of the current
required to raise a comparison tube of barium salt to the same
temperature. Both methods showed that the heat produced was at the
rate of about 135 gram calories per hour. As the emission is
continuous, one gram of radium would therefore emit about 1,180,000
gram calories in the course of a year. At the end of 2000 years it
would still emit 590,000 gram calories per year. Such a production of
energy so far surpasses all experience that it becomes almost
inconceivable. It is futile to speak of it in terms of the heat
evolved by the combustion of hydrogen, which is the greatest that can
be produced by chemical means.
This effect is unaltered at low temperatures, as has been tested by
immersing a tube containing radium in liquid air. It should be stated
that these measurements were made after the radium had reached an
equilibrium with its products; that is, after waiting at least a month
after its preparation. The evolution of heat from radium and the
radio-active substances is, in a sense, a secondary effect, as it
measures the radiant energy transformed into heat energy by the
active matter itself and whatever surrounds it. Let us repeat,
therefore, that the total amount of energy pent up in a single atom of
radium almost passes our powers of conception.
Necessity for a Disintegration Theory
The facts gathered so far justify and necessitate a theory which shall
satisfactorily explain them, and since these phenomena are not caused
by nor subject to the influence of external agencies, they must refer
to changes taking place within the atom--in other words, a theory of
disintegration. In the main, these facts may be summed up as the
emission of certain radiations from known elemental matter: the
material alpha particles with positive charge, the beta particles or
negative electrons, and the gamma rays analogous to _X_ rays. The
emission of these rays results in the production of great heat. Then
there is the law of transformations by which whole series of new
elements are generated from the original element and maintain a
constant equilibrium of growth and decay in the series. Lastly, we
have the production of helium from the alpha particles.
Disintegration Theory
In explanation of these phenomena, Rutherford offered the hypothesis
that the atoms of certain elements were unstable and subject to
disintegration. The only elements definitely known to come under this
description are the two having atoms of the greatest known mass,
thorium (232) and uranium (238).
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