A Brief Account of Radio-activityVenable, F. P. (Francis Preston)
Science
A Brief Account of Radio-activity
Venable, F. P. (Francis Preston)
Radioactivity
_i_
Pitchblende from Joachimsthal 7.0 × 10^{-11}
Clevite 1.4 × 10^{-11}
Chalcolite 5.2 × 10^{-11}
Autunite 2.7 × 10^{-11}
Carnotite 6.2 × 10^{-11}
Uranium 2.3 × 10^{-11}
Uranium and potassium sulphate 0.7 × 10^{-11}
Uranium and copper phosphate 0.9 × 10^{-11}
The last three are pure uranium and compounds of that element given
for comparison with the first five, which are naturally occurring
minerals. The last compound has the same composition as chalcolite and
is simply the artificially prepared mineral. It has the activity which
would be calculated from the proportion of uranium present, the copper
and phosphoric acid contributing no activity.
Since the activity is not dependent upon the composition but upon the
amount of uranium present, the activity in all of the minerals should
be less than that of uranium. On the contrary, it is several times
greater. Natural and artificial chalcolite also show a marked
difference in favor of the former. The supposition was a natural one,
therefore, that these minerals contained small quantities of an
element, or elements, undetected by ordinary analysis and having a
much greater activity than uranium. Similar results were obtained in
the examination of thorium minerals and thorium salts.
Discovery of Polonium
Following up this supposition, M. and Mme. Curie set themselves the
task of separating this unknown substance. Starting with pitchblende,
a systematic chemical examination was made. This is an exceedingly
complex mineral, containing many elements. The processes were
laborious and demanded much time and minute care. They need not be
described here. It is sufficient to say that along with bismuth a very
active substance was separated, to which Mme. Curie gave the name of
polonium for Poland, her native land. Its complete isolation is very
difficult and sufficient quantities of the pure substance have not
been obtained to determine its atomic weight and other properties, but
some of the lines of its spectrum have been determined. Chemically it
is very closely analogous to bismuth.
Discovery of Radium
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