A Brief History of Element Discovery, Synthesis, and AnalysisWatson, Glen W.
History
A Brief History of Element Discovery, Synthesis, and Analysis
Watson, Glen W.
Chemical elements; Chemistry -- History; Transuranium elements -- Synthesis
The early Greeks suggested earth, air, fire, and water as being the
essential material from which all others were made. Aristotle considered
these as being combinations of four properties: hot, cold, dry, and
moist (see Fig. 1).
[Illustration: Fig. 1. The elements as proposed by the early Greeks.]
Later, a fifth "essence," ether, the building material of the heavenly
bodies was added.
Paracelsus (1493-1541) introduced the three alchemical symbols salt,
sulfur, and mercury. Sulfur was the principle of combustability, salt
the fixed part left after burning (calcination), and mercury the
essential part of all metals. For example, gold and silver were
supposedly different combinations of sulfur and mercury.
Robert Boyle in his "Sceptical Chymist" (1661) first defined the word
element in the sense which it retained until the discovery of
radioactivity (1896), namely, a form of matter that could not be split
into simpler forms.
The first discovery of a true element in historical time was that of
phosphorus by Dr. Brand of Hamburg, in 1669. Brand kept his process
secret, but, as in modern times, knowledge of the element's existence
was sufficient to let others, like Kunkel and Boyle in England, succeed
independently in isolating it shortly afterward.
As in our atomic age, a delicate balance was made between the
"light-giving" (desirable) and "heat-giving" (feared) powers of a
discovery. An early experimenter was at first "delighted with the white,
waxy substance that glowed so charmingly in the dark of his laboratory,"
but later wrote, "I am not making it any more for much harm may come of
it."
Robert Boyle wrote in 1680 of phosphorus, "It shone so briskly and lookt
so oddly that the sight was extreamly pleasing, having in it a mixture
of strangeness, beauty and frightfulness."
These words describe almost exactly the impressions of eye witnesses of
the first atom bomb test at Alamagordo, New Mexico, July 16, 1945.
For the next two and three-quarters centuries the chemists had much fun
and some fame discovering new elements. Frequently there was a long
interval between discovery and recognition. Thus Scheele made chlorine
in 1774 by the action of "black manganese" (manganese dioxide) on
concentrated muriatic acid (hydrochloric acid), but it was not
recognized as an element till the work of Davy in 1810.
Occasionally the development of a new technique would lead to the "easy"
discovery of a whole group of new elements. Thus Davy, starting in 1807,
applied the method of electrolysis, using a development of Volta's pile
as a source of current; in a short time he discovered aluminum, barium,
boron, calcium, magnesium, potassium, sodium, and strontium.
The invention of the spectroscope by Bunsen and Kirchhoff in 1859
provided a new tool which could establish the purity of substances
already known and lead to the discovery of others. Thus, helium was
discovered in the sun's spectrum by Jansen and isolated from uranite by
Ramsay in 1895.
Public-domain text, read in full here on John Shaqi.
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