A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
For a long time entire reliance was placed upon the atomic weights
obtained by Berzelius, but it came to be observed that the calculation
of carbon from carbon dioxide appeared to give high results in certain
cases, so that doubt arose as to the accuracy of Berzelius’s work.
Consequently in 1840 Dumas, assisted by his pupil Stas, made a new
determination of the atomic weight of carbon, and found that the number
obtained by Berzelius, 12·12, was slightly too large. Subsequently Dumas
determined more than twenty other atomic weights, but this great amount
of work did not bring about any considerable improvement, for it appears
that Dumas did not greatly excel Berzelius in accuracy, and that the
latter had made one of his most noticeable errors in connection with
carbon.
Soon after assisting Dumas in the work upon carbon, Stas began his very
extensive and accurate, independent determinations, leading to the
publication of a book in 1867 describing his work. Stas made many
improvements in methods by the use of great care in purifying the
substances employed, and especially by using large quantities of
material in his determinations, thus diminishing the proportional errors
in weighing. His results, which dealt with most of the common elements,
were accepted with much confidence by chemists everywhere.
Stas reached the conclusion that there could be no real foundation for
Prout’s hypothesis, since so many of his atomic weights varied from
whole numbers, and this opinion has been generally accepted.
The first accurate atomic weight determination published in the Journal
was that by Mallett on lithium (=22=, 349, 1856; =28=, 349, 1859),
showing a result almost identical with that accepted at the present
time. Johnson and Allen’s determination (=35=, 94, 1863) on the rare
element cæsium was carried out with extraordinary accuracy. Lee, working
with Wolcott Gibbs, made good determinations on nickel and cobalt (=2=,
44, 1871). The work of Cooke on antimony (=15=, 41, 107, 1878) was
excellent.
Concerning the more recent work published elsewhere than in the Journal,
attention should be called particularly to the investigations that have
been carried on for the past twenty-five years by Richards and his
associates at Harvard University. Richards has shown masterly ability in
the selection of methods and in avoiding errors. His results have
displayed such marvelous agreements among repeated determinations by the
same and by different processes as to inspire the greatest confidence.
His work has been very extensive, and it is a great credit to our
country that this atomic weight work, so superior to all that has been
previously done, is being carried out here.
Public-domain text, read in full here on John Shaqi.
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