A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
There are some inconsistencies in the periodic system. The increments in
the atomic weights are irregular, and there are three cases, argon and
potassium, cobalt and nickel, and tellurium and iodine, where a higher
atomic weight is placed before a lower one in order to bring these
elements into their undoubtedly proper places. There is a peculiarity
also in the heavy-metal division of Group VIII, where three similar
elements occur in each of three places, and where the usual periodicity
appears to be suspended, or nearly so, in comparison with most of the
other elements. However, there seems to be a still more remarkable case
of this kind in Group III, where fourteen metals of the rare earths have
been placed. They are astonishingly similar in their chemical
properties, hence it seems necessary to assume that periodicity is
suspended here throughout the wide range of atomic weights from 139 to
174, where no elements save these have been found.
Several other interesting features of the table may be pointed out. The
chlorides and hydrides, as indicated by the “typical compounds,” show a
regular progression in both directions towards Group IV. (Where the
type-formulas do not apply, as far as is known, to more than one or two
elements, they have been placed in parentheses in the table given here.)
It is a striking fact that the acid-forming elements occur together in a
definite part of the table, and that the gases and other non-metallic
elements, except the inactive gases of Group VIII, occur in the same
region.
_Atomic Numbers._—As the result of a spectroscopic study of the wave
lengths or frequencies of the X-rays produced when cathode rays strike
upon anticathodes composed of different elements, Moseley in 1914
discovered that whole numbers in a simple series can be attributed to
the atoms. These atomic numbers are: 1 for hydrogen, 2 for helium, 3 for
lithium, 4 for beryllium, and so on, in the order in which the elements
occur in Mendeléeff’s periodic table, and in the cases of argon and
potassium, cobalt and nickel, and tellurium and iodine, they follow the
correct chemical order, while the atomic weights do not. They appear to
indicate, therefore, an even more fundamental relation between the atoms
than that shown by the atomic weights.
These numbers are now available for every element up to lead, and they
are particularly interesting in indicating, on account of missing
numbers, the existence of two undiscovered elements in the manganese
group, and two more among the rare-earth metals, in confirmation of the
vacant places below lead in Mendeléeff’s table.
Public-domain text, read in full here on John Shaqi.
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