A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
_The Isolation of Elements._—In the year 1818 about 53 elements were
recognized, and since that time about 30 more have been discovered, but
the elements already known comprised the more common ones, and nearly
all of those which have been commercially important. A few of them,
including beryllium, aluminium, silicon, magnesium, and fluorine, were
then known only in their compounds, as they had not yet been isolated in
the free condition.
Berzelius in 1823 prepared silicon, a non-metallic element resembling
carbon in many respects. This element has recently been prepared on a
rather large scale in electric furnaces at Niagara Falls, and has been
used for certain purposes in the form of castings.
Wöhler created much sensation in 1827 by isolating aluminium and finding
it to be a very light, strong and malleable metal, stable in the air,
and of a silver-white color. For a long time this metal was a
comparative rarity, being prepared by the reduction of aluminium
chloride with metallic sodium; but about 25 years ago Hall, an American,
devised a method of preparing it by electrolyzing aluminium oxide
dissolved in fused cryolite. This process reduced the cost of aluminium
to such an extent that it has now come into common use.
Wöhler and Bussy prepared beryllium in 1828, and Liebig and Bussy did
the same service for magnesium in 1830. The latter metal has come to be
of much practical importance, both as a very powerful reducing agent in
chemical operations, and as an ingredient of flash-light powders and of
mixtures used for fireworks. It is also used in making certain light
alloys.
After almost innumerable attempts to isolate fluorine, during a period
of nearly a century, this was finally accomplished in 1886 by Moissan in
France by the electrolysis of anhydrous hydrogen fluoride. The free
fluorine proved to be a gas of extraordinary chemical activity,
decomposing water at once with the formation of hydrogen fluoride and
ozonized oxygen. This fact explains the failure of many previous
attempts to prepare it in the presence of water.
_Early Discoveries of New Elements._—The remarkable activity of chemical
research at the beginning of our period is illustrated by the fact that
three new elements were discovered in 1817. In that year Berzelius had
discovered selenium, Arfvedson, working in Berzelius’s laboratory had
discovered the important alkali-metal lithium, and Stromeyer had
discovered cadmium.
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