A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
_The Rare Earths._—Before the year 1818 two rare earths, the oxides of
yttrium and cerium, were known in an impure condition. Since that time
about fourteen others have been discovered as associates of the first
two. The rare earths are peculiar from the fact that many of them are
always found mixed together in the minerals containing them, and also
from the circumstance that most of them are remarkably similar in their
chemical reactions and consequently exceedingly difficult to separate
from each other. In many cases multitudes of fractional precipitations
or crystallizations are needed to obtain pure salts of a number of these
metals. The solutions of the salts of several of these elements give
characteristic absorption bands when examined spectroscopically by the
use of transmitted light.
No important practical application has been found for any of these
earthy oxides, except that about one per cent of cerium oxide is mixed
with thorium oxide in incandescent gas-mantles in order to obtain
greatly increased luminosity.
_The Inactive Gases._—As long ago as 1785, Cavendish, that remarkable
Englishman who first weighed the world and first discovered the
composition of water, actually obtained a little argon in a pure
condition by sparking atmospheric nitrogen with oxygen converting it
into nitric acid (another discovery of his) and absorbing the excess of
oxygen. The volume of this residual gas as estimated by him corresponds
very closely to the volume of argon in the atmosphere, as now known.
It was more than a century later, in 1894, that Rayleigh and Ramsay
discovered argon in the air. Lord Rayleigh had found that atmospheric
nitrogen was about one-half per cent heavier than chemical nitrogen, a
fact which led to the investigation. It was only necessary to repeat
Cavendish’s experiment on a large scale, or to absorb oxygen with hot
copper and nitrogen with hot magnesium, in order to obtain argon. The
gas attracted much attention, both on account of having but a single
atom in its molecule, and particularly because it failed to enter into
chemical combination of any kind. This gas has been used of late for
filling the bulbs of incandescent electric lamps in cases where a gas
pressure without chemical action is desired.
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