A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
In 1890 and 1891, Hillebrand published in the Journal (=40=, 384, 1890:
=42=, 390, 1891) a series of analyses of the mineral uraninite and
reported in some samples of the mineral as much as 2·5 per cent of an
inactive gas. Hillebrand examined the gas spectroscopically but, just
missing an important discovery, he detected only the spectrum lines of
nitrogen. Ramsay, in searching for argon in some sort of natural
combination, and doubtless remembering Hillebrand’s work, heated some
cleveite, a variety of uraninite, and obtained, not argon, but a new
gas. This gave a yellow spectrum-line corresponding to a line previously
observed in the light of the sun’s corona and attributed to an element
in the sun called helium. Helium, therefore, in 1895 had been found on
the earth. This gas is a constant constituent of uranium minerals, as it
is produced by the breaking down of radioactive elements. It has been
found in very small quantity in the atmosphere, and is the most
difficult of all known gases to liquefy, as its boiling point, as shown
by Onnes in 1908, is only 4° above the absolute zero. It has not yet
been solidified.
In 1898 Ramsay and Travers, by the use of ingenious methods of
fractional distillation and absorption by charcoal, obtained three other
much rarer inactive gases from the atmosphere which they called neon,
krypton and xenon.
The inactive gases are all colorless, and as they form no chemical
compounds they are characterized by their densities, which give their
atomic weights, by their boiling points, and by their characteristic
Geissler-tube spectra.
The gaseous radium emanation, or niton, belongs also to the inactive
group, and it was also collected and studied by Ramsay who was compelled
to work with only 0·0001 cc. of it, as the volume obtained by heating
radium salts is very small. It is an evanescent element, disappearing
within a few days on account of radioactive disintegration. Meanwhile it
glows brilliantly when liquefied and cooled to the temperature of liquid
air. It has an atomic weight of 222, four units below that of radium,
and the difference is considered as due to the loss by radium of an atom
of helium in passing into the emanation.
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