A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
The next year in 1887, Arrhenius explained this abnormal behavior of
salts, strong acids and strong bases by assuming that they dissociate
spontaneously into ions when they dissolve, and that these more numerous
particles act like molecules in producing osmotic pressure. He showed
that these exceptional substances all conduct electricity in solution,
while those conforming with van’t Hoff’s law do not, and according to
his theory the ions become positively or negatively charged when they
are formed, and these charged ions conduct the current. For example a
molecule of sodium chloride was supposed to give the two ions Na^+ and
Cl^-, thus exerting twice as much osmotic pressure as a single molecule.
Determinations of osmotic pressure or related values, such as depression
of the freezing point and of electric conductivity, indicated that
ionization could not be regarded as complete in any case except in
exceedingly dilute solutions, and that the extent of ionization varied
with different substances. The fact that osmotic pressures and electric
conductivities gave closely agreeing results in regard to the extent of
ionization in various cases, is the strongest evidence in support of the
theory.
It was difficult at first for many chemists to believe that atoms, such
as those of sodium and chlorine, and groups such as NH_{4} and SO_{4}
could exist independently in solution, even though electrically charged.
However, the theory rapidly gained ground and is now accepted by nearly
every chemist as a satisfactory explanation of many facts.
During recent years, many investigations relating to osmotic pressure
and ionization have been carried out in the United States, but only the
work of Morse, A. A. Noyes, and the late H. C. Jones can be merely
alluded to here. It should be mentioned that the eminent author of the
ionic hypothesis gave the Silliman Memorial course of lectures at Yale
in 1911 on Theories of Solution.
_Colloidal Solutions._—Graham, an English chemist, in 1861 was the first
to make a distinction between substances forming true solutions, which
he called crystalloids, and those of a gummy nature resembling glue,
which in solution do not diffuse readily through parchment membranes, as
crystalloids do, and which he called colloids. The separation of
colloids by means of parchment was called dialysis, and this process has
come into extensive use in preparing pure colloidal solutions. Slow
diffusion is now regarded as characteristic of colloids rather than
their gummy condition.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account