A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
Colloidal solutions occupy an intermediate position between true
solutions and suspensions, resembling one or the other according to the
kind of colloid and the fineness of division. By preparing filters with
pores of varying degrees of fineness, Bechold has been able to separate
colloids from each other in accordance with the size of their particles.
It has also been possible to prepare different solutions of a colloid
varying gradually from one in which the particles were undoubtedly in
suspension to one which had many of the properties of a true solution.
Beginning in 1889, Carey Lea described in the Journal (=37=, 476, 1889
_et seq._) a variety of methods for preparing colloidal solutions of the
metals, consisting in general of treating solutions of metallic salts
with mild reducing agents. His work on colloidal silver was particularly
extensive and interesting. Solutions of this kind have recently yielded
some extremely interesting results by means of the ultra-microscope, an
apparatus devised by Zsigmondy and Siedentopf. A very intense beam of
light is passed through the solution and observed at right angles with a
powerful microscope. Under these conditions, particles much too small to
be seen by other means, reveal their presence by reflected light. It has
been possible in a very dilute solution of known strength to count the
particles and thus to calculate their size. The smallest colloidal
particles measured in this way were of gold and were shown to have
approximately ten times the diameter, or 1000 times the volume,
attributed to ordinary molecules. It is of interest that the particles
appear in rapid motion corresponding to the well-known Brownian
movement.
The chemistry of colloids has now assumed such importance that it may be
considered as a separate branch of the science. It has its own technical
journal and deals largely with the chemistry of organic products. All
living matter is built up of colloids, and hæmoglobin, starch, proteins,
rubber and milk are examples of colloidal substances or solutions. Among
inorganic substances, many sulphides, silicic acid, and the amorphous
hydroxides, like ferric hydroxide, frequently act as colloids.
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