A few secrets of the metallurgist simply toldHinkley, Gerald Watson
Science
A few secrets of the metallurgist simply told
Hinkley, Gerald Watson
Steel
For convenience we will call the mixture above mentioned, at which the
water had become thoroughly saturated with the salt, “cementite”,
because this is the name which our friends, the metallurgists, have
given to a similar mixture of iron and carbon. They call the water,
“ferrite”; the salt, “carbide” and the resulting mixture of brine,
“cementite”. This mixture of iron and carbon always exists in exactly
the same ratio, namely, 93.4% iron and 6.6% carbon, and is expressed
chemically by the symbol Fe3C, which means, in other words, that three
“atoms” of iron have united with one “_atom_” of carbon to form the
“chemical compound”, “iron carbide”, which the metallurgists, as above
mentioned, desire to term “Cementite”.
Now let us go back to the brine solution with which we are already
familiar, and suppose that we added a little more salt than the water
could absorb, and which therefore would exist in a “solid solution”,
and then bring this “mechanical mixture” to such a low temperature that
it would actually “freeze”. For convenience, and in order to agree with
the metallurgists again, let us call the resulting structure
“pearlite”. That is the name which they have given to a corresponding
“mechanical mixture” of cementite and ferrite.
This new constituent “pearlite” contains approximately O.9% carbon and
consists of inter-stratified layers or bands of ferrite and cementite.
It is regarded as a separate and distinct constituent of steel, and
takes its name from the fact that it has a mother of pearl-like
appearance under the microscope. It always occurs at a definite range
of temperature and always contains the above mentioned definite
percentage of carbon.
From the above it may be suspected that a steel containing O.9% carbon,
consisting entirely of pearlite, forms rather a special and particular
class of steels, which the metallurgists have decided to dignify with
the title “Eutectoid Steels”. Having done this much to properly impress
the unsuspecting probers of their secrets, they decided to call steels
containing less than this Eutectoid ratio of carbon (0.9% C)
“Hypo-eutectoid Steels”. These steels, of course, contain certain
definite amounts of pearlite with other amounts of free or excess
ferrite. Likewise, if the carbon content is greater than O.9% there
will be an excess of cementite over the ferrite and we will then have a
structure of pearlite plus free cementite. And these steels are spoken
of as “hyper-eutectoid” steels.
[Illustration: Hypo-eutectoid Steel. Carbon .11%. Structure:
Light—Ferrite; Dark—Pearlite. Mag. 500x]
[Illustration: Hypo-eutectoid Steel. Carbon .37%. Structure:
Light—Ferrite; Dark—Pearlite. Mag. 500x]
[Illustration: Eutectoid Steel. Carbon .90%. Structure: Fine uniform
Pearlitic condition. Mag. 500x]
[Illustration: Hyper-eutectoid Steel. Carbon 1.20%. Structure:
Dark—Pearlitic; White boundaries—Cementite. Mag. 500x]
CHAPTER III.
AN EXPERIMENT PERFORMED WITH A PIECE OF PEARLITIC STEEL.
Public-domain text, read in full here on John Shaqi.
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