What materials the ancients used for colouring glass, has not been told to us by any of their writers. It is, however, certain that metallic oxides only can be employed for that purpose, because these pigments withstand the heat of the glass furnaces; and it is highly probable that ferruginous earth, if not the sole, was at least the principal substance, by which not only all shades of red, violet, and yellow, but even a blue colour, could be communicated, as Professor Gmelin has shown[313]. Respecting the red, of which only I mean here to speak, there is the less doubt, as, at present, sometimes an artificial, and sometimes a natural, iron ochre is often employed for that purpose. For common works this is sufficient; but when pure clear glass, coloured strongly throughout with a beautiful lively red, free from flaws, and in somewhat large pieces, is required, iron is not fit, because its colour, by the continued heat necessary for making glass, either disappears or becomes dirty and almost blackish[314]. In the last century, some artists in Germany first fell upon the method of employing gold instead of iron, and of thereby making artificial rubies, which when they were well set could deceive the eye of a connoisseur, unless he tried them with a diamond or a file. The usual method was to dissolve the gold in aqua regia, and to precipitate it by a solution of tin, when it assumed the form of a purple-coloured powder. This substance, which must be mixed with the best frit, is called the precipitate of Cassius, gold-purple, or mineral-purple[315]. This Cassius, from whom it takes its name, was called Andrew, and because both the father and the son had the same christian name, they have been often confounded with each other. The father was secretary to the duke of Schleswig, and is not known as a man of letters; but the son is celebrated as the inventor or preparer of the gold-purple, and of a bezoar-essence. He took the degree of doctor at Leyden, in 1632, practised physic at Hamburg, and was appointed physician in ordinary to the bishop of Lubec. As far as I know, he never published anything respecting his art; but this service was rendered to the public by his son, who was born at Hamburg, and resided as a physician at Lubec. He was the author of a well-known treatise, now exceedingly scarce, entitled Thoughts concerning that last and most perfect work of nature, and chief of metals, gold, its wonderful properties, generation, affections, effects, and fitness for the operations of art; illustrated by experiments[316].