A History of Science — Volume 3Williams, Henry Smith
History
A History of Science — Volume 3
Williams, Henry Smith
Science -- History
Not much attention was paid to these very suggestive ideas of Davy,
because they were founded on the idea that heat is merely a motion,
which the scientific world then repudiated; but half a century later,
when the new theories of energy had made their way, there came a revival
of practically the same ideas of the particles of matter (molecules they
were now called) which Davy had advocated. Then it was that Clausius in
Germany and Clerk-Maxwell in England took up the investigation of
what came to be known as the kinetic theory of gases--the now familiar
conception that all the phenomena of gases are due to the helter-skelter
flight of the showers of widely separated molecules of which they are
composed. The specific idea that the pressure or "spring" of gases is
due to such molecular impacts was due to Daniel Bournelli, who advanced
it early in the eighteenth century. The idea, then little noticed, had
been revived about a century later by William Herapath, and again with
some success by J. J. Waterston, of Bombay, about 1846; but it gained
no distinct footing until taken in hand by Clausius in 1857 and by
Clerk-Maxwell in 1859.
The considerations that led Clerk-Maxwell to take up the computations
may be stated in his own words, as formulated in a paper "On the Motions
and Collisions of Perfectly Elastic Spheres."
"So many of the properties of matter, especially when in the gaseous
form," he says, "can be deduced from the hypothesis that their minute
parts are in rapid motion, the velocity increasing with the temperature,
that the precise nature of this motion becomes a subject of rational
curiosity. Daniel Bournelli, Herapath, Joule, Kronig, Clausius, etc.,
have shown that the relations between pressure, temperature, and density
in a perfect gas can be explained by supposing the particles to move
with uniform velocities in straight lines, striking against the sides of
the containing vessel and thus producing pressure. It is not necessary
to suppose each particle to travel to any great distance in the same
straight line; for the effect in producing pressure will be the same
if the particles strike against each other; so that the straight line
described may be very short. M. Clausius has determined the mean length
of path in terms of the average of the particles, and the distance
between the centres of two particles when the collision takes place. We
have at present no means of ascertaining either of these distances;
but certain phenomena, such as the internal friction of gases, the
conduction of heat through a gas, and the diffusion of one gas through
another, seem to indicate the possibility of determining accurately the
mean length of path which a particle describes between two successive
collisions. In order to lay the foundation of such investigations on
strict mechanical principles, I shall demonstrate the laws of motion
of an indefinite number of small, hard, and perfectly elastic spheres
acting on one another only during impact.
Public-domain text, read in full here on John Shaqi.
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