A History of Science — Volume 3Williams, Henry Smith
History
A History of Science — Volume 3
Williams, Henry Smith
Science -- History
It is sufficiently astonishing to be told that such measurements as
these have been made at all, but the astonishment grows when one hears
the results. It appears from Clerk-Maxwell's calculations that the mean
free path, or distance traversed by the molecules between collisions in
ordinary air, is about one-half-millionth of an inch; while the speed of
the molecules is such that each one experiences about eight billions
of collisions per second! It would be hard, perhaps, to cite an
illustration showing the refinements of modern physics better than
this; unless, indeed, one other result that followed directly from these
calculations be considered such--the feat, namely, of measuring the size
of the molecules themselves. Clausius was the first to point out how
this might be done from a knowledge of the length of free path; and the
calculations were made by Loschmidt in Germany and by Lord Kelvin in
England, independently.
The work is purely mathematical, of course, but the results are regarded
as unassailable; indeed, Lord Kelvin speaks of them as being absolutely
demonstrative within certain limits of accuracy. This does not mean,
however, that they show the exact dimensions of the molecule; it means
an estimate of the limits of size within which the actual size of the
molecule may lie. These limits, Lord Kelvin estimates, are about
the one-ten-millionth of a centimetre for the maximum, and the
one-one-hundred-millionth of a centimetre for the minimum. Such figures
convey no particular meaning to our blunt senses, but Lord Kelvin has
given a tangible illustration that aids the imagination to at least a
vague comprehension of the unthinkable smallness of the molecule. He
estimates that if a ball, say of water or glass, about "as large as
a football, were to be magnified up to the size of the earth, each
constituent molecule being magnified in the same proportion, the
magnified structure would be more coarse-grained than a heap of shot,
but probably less coarse-grained than a heap of footballs."
Public-domain text, read in full here on John Shaqi.
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