A History of Science — Volume 3Williams, Henry Smith
History
A History of Science — Volume 3
Williams, Henry Smith
Science -- History
Several other methods have been employed to estimate the size of
molecules. One of these is based upon the phenomena of contact
electricity; another upon the wave-theory of light; and another upon
capillary attraction, as shown in the tense film of a soap-bubble! No
one of these methods gives results more definite than that due to the
kinetic theory of gases, just outlined; but the important thing is that
the results obtained by these different methods (all of them due to Lord
Kelvin) agree with one another in fixing the dimensions of the molecule
at somewhere about the limits already mentioned. We may feel very sure
indeed, therefore, that the molecules of matter are not the unextended,
formless points which Boscovich and his followers of the eighteenth
century thought them. But all this, it must be borne in mind, refers
to the molecule, not to the ultimate particle of matter, about which we
shall have more to say in another connection. Curiously enough, we shall
find that the latest theories as to the final term of the series are
not so very far afield from the dreamings of the eighteenth-century
philosophers; the electron of J. J. Thompson shows many points of
resemblance to the formless centre of Boscovich.
Whatever the exact form of the molecule, its outline is subject to
incessant variation; for nothing in molecular science is regarded as
more firmly established than that the molecule, under all ordinary
circumstances, is in a state of intense but variable vibration. The
entire energy of a molecule of gas, for example, is not measured by its
momentum, but by this plus its energy of vibration and rotation, due
to the collisions already referred to. Clausius has even estimated
the relative importance of these two quantities, showing that the
translational motion of a molecule of gas accounts for only three-fifths
of its kinetic energy. The total energy of the molecule (which we call
"heat") includes also another factor--namely, potential energy, or
energy of position, due to the work that has been done on expanding,
in overcoming external pressure, and internal attraction between the
molecules themselves. This potential energy (which will be recovered
when the gas contracts) is the "latent heat" of Black, which so long
puzzled the philosophers. It is latent in the same sense that the energy
of a ball thrown into the air is latent at the moment when the ball
poises at its greatest height before beginning to fall.
Public-domain text, read in full here on John Shaqi.
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