A History of Science — Volume 3Williams, Henry Smith
History
A History of Science — Volume 3
Williams, Henry Smith
Science -- History
It thus appears that a variety of motions, real and potential, enter
into the production of the condition we term heat. It is, however,
chiefly the translational motion which is measurable as temperature;
and this, too, which most obviously determines the physical state of the
substance that the molecules collectively compose--whether, that is to
say, it shall appear to our blunt perceptions as a gas, a liquid, or a
solid. In the gaseous state, as we have seen, the translational motion
of the molecules is relatively enormous, the molecules being widely
separated. It does not follow, as we formerly supposed, that this
is evidence of a repulsive power acting between the molecules. The
physicists of to-day, headed by Lord Kelvin, decline to recognize any
such power. They hold that the molecules of a gas fly in straight lines
by virtue of their inertia, quite independently of one another, except
at times of collision, from which they rebound by virtue of their
elasticity; or on an approach to collision, in which latter case, coming
within the range of mutual attraction, two molecules may circle about
each other, as a comet circles about the sun, then rush apart again, as
the comet rushes from the sun.
It is obvious that the length of the mean free path of the molecules
of a gas may be increased indefinitely by decreasing the number of the
molecules themselves in a circumscribed space. It has been shown by
Professors Tait and Dewar that a vacuum may be produced artificially of
such a degree of rarefaction that the mean free path of the remaining
molecules is measurable in inches. The calculation is based on
experiments made with the radiometer of Professor Crookes, an instrument
which in itself is held to demonstrate the truth of the kinetic theory
of gases. Such an attenuated gas as this is considered by Professor
Crookes as constituting a fourth state of matter, which he terms
ultra-gaseous.
If, on the other hand, a gas is subjected to pressure, its molecules are
crowded closer together, and the length of their mean free path is thus
lessened. Ultimately, the pressure being sufficient, the molecules are
practically in continuous contact. Meantime the enormously increased
number of collisions has set the molecules more and more actively
vibrating, and the temperature of the gas has increased, as, indeed,
necessarily results in accordance with the law of the conservation
of energy. No amount of pressure, therefore, can suffice by itself to
reduce the gas to a liquid state. It is believed that even at the centre
of the sun, where the pressure is almost inconceivably great, all matter
is to be regarded as really gaseous, though the molecules must be so
packed together that the consistency is probably more like that of a
solid.
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