A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
"In order to examine the nature of the matter condensed on firing a
mixture of dephlogisticated and inflammable air, I took a glass
globe, holding 8800 grain measures, furnished with a brass cock and an
apparatus for firing by electricity. This globe was well exhausted by
an air-pump, and then filled with a mixture of inflammable and
dephlogisticated air by shutting the cock, fastening the bent glass tube
into its mouth, and letting up the end of it into a glass jar inverted
into water and containing a mixture of 19,500 grain measures of
dephlogisticated air, and 37,000 of inflammable air; so that, upon
opening the cock, some of this mixed air rushed through the bent tube
and filled the globe. The cock was then shut and the included air fired
by electricity, by means of which almost all of it lost its elasticity
(was condensed into water vapors). The cock was then again opened so as
to let in more of the same air to supply the place of that destroyed by
the explosion, which was again fired, and the operation continued till
almost the whole of the mixture was let into the globe and exploded.
By this means, though the globe held not more than a sixth part of the
mixture, almost the whole of it was exploded therein without any fresh
exhaustion of the globe."
At first this condensed matter was "acid to the taste and contained
two grains of nitre," but Cavendish, suspecting that this was due to
impurities, tried another experiment that proved conclusively that his
opinions were correct. "I therefore made another experiment," he says,
"with some more of the same air from plants in which the proportion of
inflammable air was greater, so that the burnt air was almost completely
phlogisticated, its standard being one-tenth. The condensed liquor was
then not at all acid, but seemed pure water."
From these experiments he concludes "that when a mixture of inflammable
and dephlogisticated air is exploded, in such proportions that the burnt
air is not much phlogisticated, the condensed liquor contains a little
acid which is always of the nitrous kind, whatever substance the
dephlogisticated air is procured from; but if the proportion be such
that the burnt air is almost entirely phlogisticated, the condensed
liquor is not at all acid, but seems pure water, without any addition
whatever."(2)
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account