A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
"Having procured a lens of twelve inches diameter and twenty inches
local distance, I proceeded with the greatest alacrity, by the help of
it, to discover what kind of air a great variety of substances would
yield, putting them into the vessel, which I filled with quicksilver,
and kept inverted in a basin of the same .... With this apparatus, after
a variety of experiments.... on the 1st of August, 1774, I endeavored
to extract air from mercurius calcinatus per se; and I presently found
that, by means of this lens, air was expelled from it very readily.
Having got about three or four times as much as the bulk of my
materials, I admitted water to it, and found that it was not imbibed
by it. But what surprised me more than I can express was that a candle
burned in this air with a remarkably vigorous flame, very much like that
enlarged flame with which a candle burns in nitrous oxide, exposed to
iron or liver of sulphur; but as I had got nothing like this remarkable
appearance from any kind of air besides this particular modification of
vitrous air, and I knew no vitrous acid was used in the preparation of
mercurius calcinatus, I was utterly at a loss to account for it."(4)
The "new air" was, of course, oxygen. Priestley at once proceeded to
examine it by a long series of careful experiments, in which, as will
be seen, he discovered most of the remarkable qualities of this gas.
Continuing his description of these experiments, he says:
"The flame of the candle, besides being larger, burned with more
splendor and heat than in that species of nitrous air; and a piece of
red-hot wood sparkled in it, exactly like paper dipped in a solution of
nitre, and it consumed very fast; an experiment that I had never thought
of trying with dephlogisticated nitrous air.
"... I had so little suspicion of the air from the mercurius calcinatus,
etc., being wholesome, that I had not even thought of applying it to
the test of nitrous air; but thinking (as my reader must imagine I
frequently must have done) on the candle burning in it after long
agitation in water, it occurred to me at last to make the experiment;
and, putting one measure of nitrous air to two measures of this air, I
found not only that it was diminished, but that it was diminished quite
as much as common air, and that the redness of the mixture was likewise
equal to a similar mixture of nitrous and common air.... The next day I
was more surprised than ever I had been before with finding that, after
the above-mentioned mixture of nitrous air and the air from mercurius
calcinatus had stood all night,... a candle burned in it, even better
than in common air."
Public-domain text, read in full here on John Shaqi.
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