A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
Lavoisier's observations on combustion are at once important and
interesting: "Combustion," he says, "... is the decomposition of oxygen
produced by a combustible body. The oxygen which forms the base of this
gas is absorbed by and enters into combination with the burning body,
while the caloric and light are set free. Every combustion necessarily
supposes oxygenation; whereas, on the contrary, every oxygenation
does not necessarily imply concomitant combustion; because combustion
properly so called cannot take place without disengagement of caloric
and light. Before combustion can take place, it is necessary that the
base of oxygen gas should have greater affinity to the combustible body
than it has to caloric; and this elective attraction, to use Bergman's
expression, can only take place at a certain degree of temperature which
is different for each combustible substance; hence the necessity of
giving the first motion or beginning to every combustion by the approach
of a heated body. This necessity of heating any body we mean to burn
depends upon certain considerations which have not hitherto been
attended to by any natural philosopher, for which reason I shall enlarge
a little upon the subject in this place:
"Nature is at present in a state of equilibrium, which cannot have been
attained until all the spontaneous combustions or oxygenations possible
in an ordinary degree of temperature had taken place.... To illustrate
this abstract view of the matter by example: Let us suppose the usual
temperature of the earth a little changed, and it is raised only to the
degree of boiling water; it is evident that in this case phosphorus,
which is combustible in a considerably lower degree of temperature,
would no longer exist in nature in its pure and simple state, but would
always be procured in its acid or oxygenated state, and its radical
would become one of the substances unknown to chemistry. By gradually
increasing the temperature of the earth, the same circumstance would
successively happen to all the bodies capable of combustion; and, at
the last, every possible combustion having taken place, there would
no longer exist any combustible body whatever, and every substance
susceptible of the operation would be oxygenated and consequently
incombustible.
Public-domain text, read in full here on John Shaqi.
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