A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
"The only substance that I could now conceive as furnishing the fixed
alkali was the water itself. This water appeared pure by the tests of
nitrate of silver and muriate of barytes; but potash of soda, as is
well known, rises in small quantities in rapid distillation; and the
New River water which I made use of contains animal and vegetable
impurities, which it was easy to conceive might furnish neutral
salts capable of being carried over in vivid ebullition."(1) Further
experiment proved the correctness of this inference, and the last doubt
as to the origin of the puzzling chemical was dispelled.
Though the presence of the alkalies and acids in the water was
explained, however, their respective migrations to the negative and
positive poles of the battery remained to be accounted for. Davy's
classical explanation assumed that different elements differ among
themselves as to their electrical properties, some being positively,
others negatively, electrified. Electricity and "chemical affinity," he
said, apparently are manifestations of the same force, acting in the one
case on masses, in the other on particles. Electro-positive particles
unite with electro-negative particles to form chemical compounds, in
virtue of the familiar principle that opposite electricities attract
one another. When compounds are decomposed by the battery, this mutual
attraction is overcome by the stronger attraction of the poles of the
battery itself.
This theory of binary composition of all chemical compounds, through the
union of electro-positive and electro-negative atoms or molecules,
was extended by Berzelius, and made the basis of his famous system of
theoretical chemistry. This theory held that all inorganic compounds,
however complex their composition, are essentially composed of such
binary combinations. For many years this view enjoyed almost undisputed
sway. It received what seemed strong confirmation when Faraday showed
the definite connection between the amount of electricity employed and
the amount of decomposition produced in the so-called electrolyte. But
its claims were really much too comprehensive, as subsequent discoveries
proved.
ORGANIC CHEMISTRY AND THE IDEA OF THE MOLECULE
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