A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
But a consideration of this condition of stable equilibrium in the
molecule at once suggests a new question: How can an aggregation of
atoms, having all their affinities satisfied, take any further part in
chemical reactions? Seemingly such a molecule, whatever its physical
properties, must be chemically inert, incapable of any atomic
readjustments. And so in point of fact it is, so long as its component
atoms cling to one another unremittingly. But this, it appears, is
precisely what the atoms are little prone to do. It seems that they are
fickle to the last degree in their individual attachments, and are as
prone to break away from bondage as they are to enter into it. Thus the
oxygen atom which has just flung itself into the circuit of two
hydrogen atoms, the next moment flings itself free again and seeks
new companions. It is for all the world like the incessant change
of partners in a rollicking dance. This incessant dissolution and
reformation of molecules in a substance which as a whole remains
apparently unchanged was first fully appreciated by Ste.-Claire Deville,
and by him named dissociation. It is a process which goes on much more
actively in some compounds than in others, and very much more actively
under some physical conditions (such as increase of temperature) than
under others. But apparently no substances at ordinary temperatures,
and no temperature above the absolute zero, are absolutely free from its
disturbing influence. Hence it is that molecules having all the
valency of their atoms fully satisfied do not lose their chemical
activity--since each atom is momentarily free in the exchange of
partners, and may seize upon different atoms from its former partners,
if those it prefers are at hand.
Public-domain text, read in full here on John Shaqi.
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