A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
But in 1844 Faraday returned to them, armed now with new weapons, in the
way of better air-pumps and colder freezing mixtures, which the labors
of other workers, chiefly Thilorier, Mitchell, and Natterer, had made
available. With these new means, and without the application of any
principle other than the use of cold and pressure as before, Faraday now
succeeded in reducing to the liquid form all the gases then known with
the exception of six; while a large number of these substances were
still further reduced, by the application of the extreme degrees of
cold now attained, to the condition of solids. The six gases which still
proved intractable, and which hence came to be spoken of as "permanent
gases," were nitrous oxide, marsh gas, carbonic oxide, oxygen, nitrogen,
and hydrogen.
These six refractory gases now became a target for the experiments of a
host of workers in all parts of the world. The resources of mechanical
ingenuity of the time were exhausted in the effort to produce low
temperatures on the one hand and high pressures on the other. Thus
Andrews, in England, using the bath of solid carbonic acid and ether
which Thilorier had discovered, and which produces a degree of cold
of--80° Centigrade, applied a pressure of five hundred atmospheres, or
nearly four tons to the square inch, without producing any change of
state. Natterer increased this pressure to two thousand seven hundred
atmospheres, or twenty-one tons to the square inch, with the same
negative results. The result of Andrews' experiments in particular was
the final proof of what Cagniard de la Tour had early suspected
and Faraday had firmly believed, that pressure alone, regardless of
temperature, is not sufficient to reduce a gas to the liquid state. In
other words, the fact of a so-called "critical temperature," varying
for different substances, above which a given substance is always a gas,
regardless of pressure, was definitively discovered. It became clear,
then, that before the resistant gases would be liquefied means of
reaching extremely low temperatures must be discovered. And for this,
what was needed was not so much new principles as elaborate and
costly machinery for the application of a principle long familiar--the
principle, namely, that an evaporating liquid reduces the temperature of
its immediate surroundings, including its own substance.
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