A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
Another commercial use to which refrigerator machines are now put is in
the manufacture of various drugs, where absolute purity is desirable.
As different substances congeal at different temperatures, but the same
substances at uniform pressure always at the same temperature, a
means is afforded of freeing a drug from impurities by freezing, where
sometimes the same result cannot be accomplished with like thoroughness
by any other practicable means. Indeed, by this means impurities have
been detected where not previously suspected. And Professor Ramsay has
detected some new elementary substances even, as constituents of the
air, which had previously not been dissociated from the nitrogen with
which they are usually mixed.
Such applications of the refrigerator principles as these, however,
though of vast commercial importance, are held by many enthusiasts to
be but a bagatelle compared with other uses to which liquefied gases
may some time be put. Their expectations are based upon the enormous
potentialities that are demonstrably stored in even a tiny portion of,
say, liquefied air. These are, indeed, truly appalling. Consider, for
example, a portion of air at a temperature above its critical point, to
which, as in Thilorier's experiments, a pressure of thirty-one tons to
the square inch of the encompassing wall is being applied. Recall that
action and reaction are equal, and it is apparent that the gas itself is
pushing back--struggling against being compressed, if you will--with an
equal power. Suppose the bulk of the gas is such that at this pressure
it occupies a cubical space six inches on a side--something like the
bulk of a child's toy balloon, let us say. Then the total outward
pressure which that tiny bulk of gas exerts, in its desperate molecular
struggle, is little less than five thousand tons. It would support an
enormous building without budging a hair's-breadth. If the building
weighed less than five thousand tons it would be lifted by the gas; if
much less it would be thrown high into the air as the gas expanded. It
gives one a new sense of the power of numbers to feel that infinitesimal
atoms, merely by vibrating in unison, could accomplish such a result.
But now suppose our portion of gas, instead of being placed under our
hypothetical building, is plunged into a cold medium, which will permit
its heat-vibrations to exhaust themselves without being correspondingly
restored. Then, presently, the temperature is lowered below the critical
point, and, presto! the mad struggle ceases, the atoms lie amicably
together, and the gas has become a liquid. What a transformed thing
it is now. Instead of pressing out with that enormous force, it has
voluntarily contracted as the five thousand tons pressure could not
make it do; and it lies there now, limpid and harmless-seeming, in the
receptacle, for all the world like so much water.
Public-domain text, read in full here on John Shaqi.
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