A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Comparative permanence of Photographs under the action of
Sulphur._--_Developed_ Positives, as a rule, stand better than those
printed by direct exposure to light; but much depends upon the nature of
the negative process followed; and hence no general statement can be made
which will not be liable to many exceptions. The mode of conducting the
development must not be overlooked. The prints, which become very red in
the Hyposulphite fixing Bath from the action of the developer having been
stopped at too early a period, are often sulphuretted and destroyed even
more readily than a vigorous sun-print obtained by direct exposure to
light.
A point of even greater importance is _the nature of the sensitive
surface_ which receives the latent image. It is the print _developed upon
Iodide of Silver_ which especially resists sulphuration. In that case,
not only is the preliminary toning effect of the Sulphur more slow than
usual, but the impression cannot be made to fade by any continuance of the
action. It loses much of its brilliancy, and is reduced in intensity, but
it is not so completely destroyed as to be useless. The reason of this, as
shown in the last paper, depends upon the fact that the Talbotype proofs
contain the largest amount of Silver in the image.
The employment of Gold in toning does not render an ordinary sun-print
as permanent as a Positive developed upon Iodide of Silver. The deep
shadows of the picture are protected by the Gold, but the lighter shades
not so perfectly. Hence after the Sulphur has acted, in place of the
universal yellow and faded aspect presented by the simple untoned print,
the Positive fully toned by Gold has black shadows with yellow half-tones.
Therefore, whilst recommending the use of Gold as a toning agent, it does
not seem advisable to lay too much stress upon it as a preservative from
the destructive action of Sulphur.
_Exposure of Positive Prints to a Sulphuretting Atmosphere._--In testing
the action of a solution of Sulphuretted Hydrogen upon paper Positives,
it did not appear that the conditions under which the prints were placed
bore a sufficiently close resemblance to the case of Positives exposed
to an atmosphere contaminated with _minute traces_ of the gas; and this
more particularly because it is known that _dry_ Sulphuretted Hydrogen has
comparatively little effect upon Photographic Prints.
The experiments were therefore repeated in a somewhat different form.
A number of Positives (about three dozen) printed in various ways,
were suspended in a glass case, measuring 2-1/2 feet by 21 inches,
and containing 7-1/2 cubic feet of air; into which was introduced,
occasionally, a few bubbles of Sulphuretted Hydrogen, just sufficient to
keep the air of the chamber smelling perceptibly of the gas. A polished
Daguerreotype plate was hung up in the centre, to serve as a guide to the
progress of the sulphuretting action.
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