A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Of prints obtained by the ordinary process of direct exposure to light,
those on plain paper are the first to fade, the oxidizing action being
most seen upon the _half-tones_. The use of _Albumen_ gives a great
advantage. Developed prints on Albumen stand far better than the same
upon plain paper; and even the Albuminized sun prints are less injured by
the Permanganate than the best of the Negative prints prepared without
Albumen. Caseine has the same effect, but to a less extent; and as Serum
of Milk almost invariably contains uncoagulated Caseine, its efficacy is
thus explained.
The manner of toning the print is a point of importance; previous
sulphuration in an old Hyposulphite Bath always facilitating the oxidizing
action.
_Action of Chlorine upon Positive Prints._--Aqueous solution of Chlorine
destroys the Photographic image, changing it first to a violet tint
(probably Subchloride), and subsequently obliterating it by conversion
into white Chloride of Silver. The impression, although invisible,
remains in the paper, and may be developed in the form of yellow or brown
Sulphuret of Silver by the action of Sulphuretted Hydrogen. It also
becomes visible on exposure to light, and assumes considerable intensity
if the paper be previously brushed with free Nitrate of Silver. Sulphate
of Iron produces no effect upon the invisible image of Chloride of Silver;
but Gallic or Pyrogallic Acid, rendered alkaline by Potash, converts it
into a black deposit.
The Action of Chlorine water usually commences at the edges and corners of
the print, in the same manner as that of oxidizing agents. The proofs upon
Albumen are the least readily injured, and next, those developed on Iodide
of Silver.
_Hydrochloric Acid._--The liquid acid of sp. gr. ·116, even when free from
Chlorine, acts immediately upon the half-tones of a positive print, and
destroys the full shadows in the course of a few hours; a slight residual
colour however usually remains in the darkest parts. The prints developed
on Iodide of Silver are the most permanent.
_Sulphuric, Acetic Acids, etc._--Acids of all kinds appear to exert an
injurious influence upon Positive prints, and especially so upon the
half-tones of the image, the effect varying with the strength of the acid
and the degree of dilution with water. Even a vegetable acid like Acetic
gradually darkens the colour and destroys partially or entirely the faint
outlines of the picture.
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