A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Nitric Acid applied in a concentrated form acts immediately upon the
darkened surface, bleaching every part of the print with the exception
of the bronzed shadows, which usually retain a slight residual colour. A
solution of Chromic Acid is still more active. This liquid may usefully be
applied to distinguish prints toned by Sulphur from others toned by Gold;
the presence of metallic Gold protecting the shadows of the picture in
some measure from the action of the acid. The solution should be prepared
as follows:--
Bichromate of Potash 6 grains.
Strong Sulphuric Acid 4 minims.
Water 12 ounces.
A solution of Permanganate of Potash is an energetic destroyer of paper
positives; and, as it is a neutral substance, may conveniently be employed
in testing the relative capability of withstanding oxidation possessed
by different Photographic Prints. The solution should be dilute, of a
pale pink hue, and the Positives must be moved occasionally, as the first
effect is to decolorize a great portion of the liquid, the Permanganate
oxidizing the size and organic tissue of the paper. After an immersion
of twenty minutes to half an hour, varying with the degree of dilution,
the half-tones of the picture begin to die out, and the full shadows
become darker in colour; the bronzed portions of the print withstand the
action longer, but at length the whole is changed to a yellow image much
resembling in appearance the Photograph faded by Sulphur.
_Comparative permanence of Photographs treated with Permanganate of
Potash._--Developed prints prepared by a Negative process withstand the
action better than others. But to this rule there are exceptions; much
depending upon the time of exposure to light, and the extent to which
the development is carried. Those prints which, being exposed for a
short time, and afterwards strongly developed, become dark in colour and
vigorous in outline, are more permanent than others which having been
over-exposed and under-developed, lose their dark colour and become red
and comparatively faint in the Hyposulphite fixing Bath.
Positives developed upon a surface of _Chloride_ of Silver on plain paper
do not resist the oxidizing action so perfectly as those on Iodide of
Silver. Prints developed upon paper prepared with Serum of Milk containing
Caseine stand better than those on plain paper.
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