A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Heat, moist and dry._--Long-continued boiling in distilled water has
a reddening action upon Positive Prints. The image becomes at length
pale and faint, resembling a print treated with Ammonia before toning.
A deposit of Gold upon the image lessens, but does not altogether
neutralize, the effect of the hot water. If the boiling be long continued,
the violet-purple tone often imparted by the Gold invariably gives place
to a chocolate-brown, which appears to be the most permanent colour.
Prints _developed_ by Gallic Acid upon paper prepared with Serum of Milk
or with a Citrate, suffer as much as others obtained by direct action of
light. Ammonio-Nitrate prints on highly salted paper, which become nearly
black when toned with Gold, retain their original appearance the most
perfectly; a slight diminution of brightness being the only observable
difference after long boiling in water. Albumen proofs, and prints on
English papers, or foreign papers prepared with Serum of Milk, Citrates,
Tartrates, or any of those bodies which _redden_ the reduced Salt, are,
as a rule, rendered lighter in colour, and pass from purple to brown when
boiled in water.
Dry heat has an opposite effect to that of hot water, usually _darkening_
the colour of the image. On exposing a plain paper print simply fixed, and
thoroughly freed from Hyposulphite of Soda by washing, to a current of
heated air, it changes gradually from red to dark brown, in which state
it continues until the temperature rises to the point at which the paper
begins to char, when it resumes its original red tone, becoming at the
same time faint and indistinct.
_The Products of Combustion of Coal-gas a cause of Fading._--Coal-gas
contains Sulphur compounds, which in combustion are oxidized into
Sulphurous and Sulphuric Acids; other substances of a deleterious nature
may also be present. A plate of polished silver suspended in a glass tube,
through which was directed the current of heated air rising from a small
gas jet, became tarnished with a white film in the course of twenty-four
hours. Positive prints exposed to the same, absorbed moisture and faded;
the action resembling that of oxidation, in being preceded by a general
darkening in colour. Of four prints exposed, an Iodide-developed print was
the least injured, and next, a print upon Albuminized paper.
ON THE ACTION OF DAMP AIR UPON POSITIVE PRINTS.
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