A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_On a means of Multiplying Photographic Impressions, and other Discoveries
of Mr. Fox Talbot._--The first communication made to the Royal Society
by Mr. Fox Talbot, in January, 1839, included only the preparation of a
sensitive paper for copying objects by application. It was directed that
the paper should be dipped first in solution of Chloride of Sodium, and
then in Nitrate of Silver. In this way a white substance termed Chloride
of Silver is formed, more sensitive to light than the Nitrate of Silver
originally employed by Wedgwood and Davy. The object is laid in contact
with the prepared paper, and, being exposed to light, a copy is obtained,
which is Negative,--_id est_, with the light and shade reversed. A second
sheet of paper is then prepared, and the first, or Negative impression,
laid upon it, so as to allow the sun's light to pass through the
transparent parts. Under these circumstances, when the Negative is raised,
a natural representation of the object is found below; the tints having
been again reversed by the second operation.
This production of a Negative Photograph, from which any number of
Positive copies may be obtained, is a cardinal point in Mr. Talbot's
invention, and one of great importance.
The patent issued for the process named Talbotype or Calotype dates from
February, 1841. A sheet of paper is first coated with Iodide of Silver by
soaking it alternately in Iodide of Potassium and Nitrate of Silver; it
is then washed with solution of Gallic Acid containing Nitrate of Silver
(sometimes termed Gallo-Nitrate of Silver), by which the sensibility to
light is greatly augmented. An exposure in the Camera of some seconds or
minutes, according to the brightness of the light, impresses an invisible
image, which is brought out by treating the plate with a fresh portion of
the mixture of Gallic Acid and Nitrate of Silver employed in exciting.
On the use of Glass Plates to retain Sensitive Films.--The principal
defects in the Calotype process are attributable to the coarse and
irregular structure of the fibre of paper, even when manufactured with the
greatest care, and expressly for Photographic purposes. In consequence of
this, the same amount of exquisite definition and sharpness of outline as
that resulting from the use of metal plates, cannot be obtained.
We are indebted to Sir John Herschel for the first employment of glass
plates to receive sensitive Photographic films.
The Iodide of Silver may be retained upon the glass by means of a layer of
Albumen or white of egg, as proposed by M. Niépce de Saint-Victor, nephew
to the original discoverer of the same name.
A more important improvement still is the employment of "Collodion" for a
similar purpose.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account