A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Dissolve the Nitrate of Silver in 2 ounces of the water, then from the
total quantity of Hyposulphite of Soda, weigh out
Hyposulphite of Soda 2 drachms;
dissolve this likewise in 2 ounces of water, and the remainder of the
Hyposulphite in the other 4 ounces. Then, having the three solutions in
separate vessels, pour the Nitrate of Silver at once into the 2-ounce
solution of Hyposulphite, agitating the precipitated Hyposulphite of
Silver rapidly. In a short time it will begin to decompose, passing from
white to canary-yellow, and then to orange-yellow. _When the orange-yellow
begins to verge towards brown_, add the 4-ounce concentrated solution of
Hyposulphite, which will at once complete the decomposition, a part of the
precipitate dissolving and the remainder becoming perfectly black. After
filtering out the black Sulphuret of Silver, the solution is ready for use.
A Bath prepared by this formula is not usually very active, but it shows
clearly the process by which an ordinary fixing Bath may be converted into
a toning Bath by the immersion of positives having free Nitrate of Silver
upon the surface.
The following formula is more economical and gives a better result, but
it cannot be used for "Ammonio-Nitrate" prints; the addition of an alkali
precipitating Sulphuret of Iron.
Strong solution of Perchloride of Iron 6 fluid drachms.
Hyposulphite of Soda 4 ounces.
Water 8 ounces.
Nitrate of Silver 30 grains.
Dissolve the Hyposulphite of Soda in seven ounces of the water, the
Nitrate of Silver in the remaining one ounce; then pour the Perchloride of
Iron into the solution of Hyposulphite, by degrees, stirring all the time.
The addition of the Iron Salt strikes a fine purple colour, but this soon
disappears. When the liquid has become again colourless, which it does
in a few minutes, add the Nitrate of Silver, stirring briskly. Perfect
solution will take place without any formation of black Sulphuret.
A toning Bath prepared with Chloride of Iron will be ready for use twelve
hours after mixing, but it will be more active at the expiration of a
week. The solution is acid to test-paper, and _milky_ from a deposit of
Sulphur, which must be filtered out.
The Perchloride of Iron should be prepared by boiling Peroxide of
Iron with Hydrochloric Acid, in preference to dissolving Iron wire in
Aqua-Regia.
The addition of the Nitrate of Silver is made in order to produce a
portion of Hyposulphite of Silver in the bath; the presence of a Silver
Salt having been found to modify the tint of the Positives, and to prevent
their quickly turning yellow.
SECTION IV.
_On the Fading of Photographic Prints._
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