A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
For many years subsequent to the discovery of the process of Photographic
Printing by Mr. Fox Talbot, it was not generally known that pictures so
produced were easily susceptible of injury from various causes, and in
particular from traces of the _fixing-agent_ remaining in the paper.
Hence, due care not being taken in the proper cleansing and preservation
of the proofs, the majority of them faded.
This matter became at last one of such importance that the Council of the
Photographic Society decided upon forming a Committee for the purpose of
examining the subject. The Author was honoured by being placed upon this
Committee, and the researches of which an abstract has been given in the
previous Section, were undertaken at the request of the Society.
The present Section is intended to explain practically and in a
concise manner the causes of the fading of Photographic Prints, and
the precautions which should be taken to ensure their permanency. The
chemistry of the subject having been fully explained in the last Section,
it will suffice to refer the reader to its pages for more detailed
information.
_Historical evidence of the permanence of Photographs._--It is a point of
interest to collect information as to the existence of old Photographs
which have remained many years unchanged. There are numerous instances
of Positives printed more than ten years ago, which have not perceptibly
altered up to the present time. These prints are mostly on plain paper,
Albumen not having come into use at so early a date. The general
impression of practical operators however is, that fading has occurred
less frequently since the introduction of Albuminized paper.
Positives printed by development on paper prepared by Talbot's method
seem as a rule to have stood remarkably well, and instances of Talbotype
Negatives having faded are rare.
Of the prints which have proved to be permanent, some are red or brown in
colour, but many, being of a dark or purple shade, have evidently been
toned, although not with Gold, the use of which was unknown to the earlier
Photographers.
It is plain from data thus collected, that Photographs do not necessarily
fade by time; and the fact that in one and the same portfolio are
constantly seen prints which appear permanent, and others in an advanced
state of change, cannot but lead to the inference that the main causes of
deterioration are intrinsic, depending upon some injurious matters left in
the paper; which is confirmed by experiment.
_Causes of fading._--The Author believes that the fading of Photographic
Prints may almost invariably be referred to one or other of the following
conditions:--
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